(3'R,4'R)-pyriculol

Base Information

Chemical Name:(3'R,4'R)-pyriculol
CAS No.:113731-37-6
Molecular Formula:C₁₄H₁₆O₄
Molecular Weight:248.279
Hs Code.:

Synonyms:(3'R,4'R)-pyriculol

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Chemical Property of (3'R,4'R)-pyriculol

Chemical Property:

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Technology Process of (3'R,4'R)-pyriculol

There total 21 articles about (3'R,4'R)-pyriculol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 2-((E)-2-((4R,5R)-2,2-dimethyl-5-((E)-prop-1-en-1-yl)-1,3-dioxolan-4-yl)vinyl)-6-hydroxybenzaldehyde

: 113731-37-6
(3'R,4'R)-pyriculol

Guidance literature:: With hydrogenchloride; water; In tetrahydrofuran; at 20 ℃; for 3h;
DOI:10.1016/j.tet.2020.131368

Reference yield: 75.0%

: 113776-08-2
(3'R,4'R)-pyriculol-3',4'-carbonate

: 113731-37-6
(3'R,4'R)-pyriculol

Guidance literature:: With potassium carbonate; In methanol; water; for 4h; Ambient temperature;
DOI:10.1271/bbb1961.51.2161

Reference yield:

: 526-75-0
2,3-Dimethylphenol

: 113731-37-6
(3'R,4'R)-pyriculol

Guidance literature:: Multi-step reaction with 9 steps

1.1: triethylamine / dichloromethane / 0.17 h / 0 °C

2.1: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / tetrachloromethane / Reflux

2.2: 36 h / Reflux

3.1: potassium hexamethylsilazane / tetrahydrofuran / 0.5 h / -78 °C

3.2: 12 h

4.1: hydrogen fluoride; pyridine / tetrahydrofuran / 0 - 20 °C

5.1: lithium triethylborohydride / tetrahydrofuran; diethyl ether / 0.17 h / -78 °C

6.1: toluene-4-sulfonic acid / acetone / 20 °C

7.1: lithium aluminium tetrahydride / tetrahydrofuran / 0 - 20 °C

8.1: manganese(IV) oxide / dichloromethane / 20 °C

9.1: hydrogenchloride; water / tetrahydrofuran / 3 h / 20 °C

With pyridine; hydrogenchloride; manganese(IV) oxide; N-Bromosuccinimide; lithium aluminium tetrahydride; 2,2'-azobis(isobutyronitrile); hydrogen fluoride; water; potassium hexamethylsilazane; lithium triethylborohydride; toluene-4-sulfonic acid; triethylamine; In tetrahydrofuran; tetrachloromethane; diethyl ether; dichloromethane; acetone;
DOI:10.1016/j.tet.2020.131368