O- Se-phenyl selenocarbonate

Base Information

• Chemical Name: O- Se-phenyl selenocarbonate
• CAS No.: 105702-04-3
• Molecular Formula: C₂₁H₂₀O₂Se
• Molecular Weight: 383.349
• Mol file: 105702-04-3.mol

Synonyms:O- Se-phenyl selenocarbonate

Chemical Property of O- Se-phenyl selenocarbonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of O- Se-phenyl selenocarbonate

There total 4 articles about O- Se-phenyl selenocarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

Benzeneselenol (645-96-5) + C15H15ClO2 → O- Se-phenyl selenocarbonate (105702-04-3)

Guidance literature:

With pyridine; In benzene; for 1h;

DOI:10.1021/jo00043a030

Reference yield:

trans-2-(2-phenylethynyl)-1-cyclohexanol (82031-71-8,82032-02-8,138907-21-8) → O- Se-phenyl selenocarbonate (105702-04-3)

Guidance literature:

Multi-step reaction with 2 steps

1: N(Et)3 / benzene / Ambient temperature

2: 84 percent / pyridine / benzene / 1 h

With pyridine; triethylamine; In benzene;

DOI:10.1021/jo00043a030

Reference yield:

cyclohexane-1,2-epoxide (286-20-4) → O- Se-phenyl selenocarbonate (105702-04-3)

Guidance literature:

Multi-step reaction with 3 steps

1: boron trifluoride etherate

3: pyridine

With pyridine; boron trifluoride diethyl etherate;

DOI:10.1016/S0040-4039(00)84062-9

upstream raw materials:

Benzeneselenol

trans-2-(2-phenylethynyl)-1-cyclohexanol

cyclohexane-1,2-epoxide

lithium phenylacetylide

Downstream raw materials:

trans-hexahydro-3-benzylidene-2(3H)-benzofuranone

trans-hexahydro-3-benzylidene-2(3H)-benzofuranone

(3aS,7aR)-3-[1-Phenyl-meth-(E)-ylidene]-hexahydro-benzofuran-2-one