methyl (1R,2S,2'R,4S)-4-<2'-acetoxy-2'-phenylacetoxy>-2-<(trityloxy)methyl>cyclopentaneacetate

Base Information

Chemical Name:methyl (1R,2S,2'R,4S)-4-<2'-acetoxy-2'-phenylacetoxy>-2-<(trityloxy)methyl>cyclopentaneacetate
CAS No.:149551-09-7
Molecular Formula:C₃₈H₃₈O₇
Molecular Weight:606.716
Hs Code.:

Synonyms:methyl (1R,2S,2'R,4S)-4-<2'-acetoxy-2'-phenylacetoxy>-2-<(trityloxy)methyl>cyclopentaneacetate

Suppliers and Price of methyl (1R,2S,2'R,4S)-4-<2'-acetoxy-2'-phenylacetoxy>-2-<(trityloxy)methyl>cyclopentaneacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl (1R,2S,2'R,4S)-4-<2'-acetoxy-2'-phenylacetoxy>-2-<(trityloxy)methyl>cyclopentaneacetate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl (1R,2S,2'R,4S)-4-<2'-acetoxy-2'-phenylacetoxy>-2-<(trityloxy)methyl>cyclopentaneacetate

There total 7 articles about methyl (1R,2S,2'R,4S)-4-<2'-acetoxy-2'-phenylacetoxy>-2-<(trityloxy)methyl>cyclopentaneacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 13360-81-1,15507-06-9,42070-72-4,42070-82-6,67505-46-8,67671-05-0,67671-06-1,69831-10-3,95-12-5
5-norbornene-2-methanol

: 149551-09-7
methyl (1R,2S,2'R,4S)-4-<2'-acetoxy-2'-phenylacetoxy>-2-<(trityloxy)methyl>cyclopentaneacetate

Guidance literature:: Multi-step reaction with 6 steps

1: 100 percent / pyridine, Bu₄N(ClO₄) / CH₂Cl₂ / 4.5 h / Ambient temperature

2: 1) (+)-(1R)-α-pinene, BH3-THF, 2) 30percent aq. H2O2, 3N aq. NaOH, NaHSO3

3: pyridinium chlorochromate, Celite / CH₂Cl₂ / 4 h / Ambient temperature

4: NaHCO₃, 3-chloroperbenzoic acid / CH₂Cl₂ / 18 h / 4 °C

5: methanol / Heating

6: PPh₃, diethyl azodicarboxylate / tetrahydrofuran / 3 h / Ambient temperature

With pyridine; sodium hydroxide; borane-THF; Celite; tetrabutylammonium perchlorate; dihydrogen peroxide; sodium hydrogencarbonate; 2,6,6-trimethylbicyclo[3.1.1]hept-2-ene; sodium hydrogensulfite; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; pyridinium chlorochromate; diethylazodicarboxylate; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1002/hlca.19930760207

Reference yield:

: 76-83-5
trityl chloride

: 149551-09-7
methyl (1R,2S,2'R,4S)-4-<2'-acetoxy-2'-phenylacetoxy>-2-<(trityloxy)methyl>cyclopentaneacetate

Guidance literature:: Multi-step reaction with 6 steps

1: 100 percent / pyridine, Bu₄N(ClO₄) / CH₂Cl₂ / 4.5 h / Ambient temperature

2: 1) (+)-(1R)-α-pinene, BH3-THF, 2) 30percent aq. H2O2, 3N aq. NaOH, NaHSO3

3: pyridinium chlorochromate, Celite / CH₂Cl₂ / 4 h / Ambient temperature

4: NaHCO₃, 3-chloroperbenzoic acid / CH₂Cl₂ / 18 h / 4 °C

5: methanol / Heating

6: PPh₃, diethyl azodicarboxylate / tetrahydrofuran / 3 h / Ambient temperature

With pyridine; sodium hydroxide; borane-THF; Celite; tetrabutylammonium perchlorate; dihydrogen peroxide; sodium hydrogencarbonate; 2,6,6-trimethylbicyclo[3.1.1]hept-2-ene; sodium hydrogensulfite; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; pyridinium chlorochromate; diethylazodicarboxylate; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1002/hlca.19930760207

Reference yield:

: 5-exo-<(trityloxy)methyl>bicyclo<2.2.1>hept-2-ene

: 149551-09-7
methyl (1R,2S,2'R,4S)-4-<2'-acetoxy-2'-phenylacetoxy>-2-<(trityloxy)methyl>cyclopentaneacetate

Guidance literature:: Multi-step reaction with 5 steps

1: 1) (+)-(1R)-α-pinene, BH3-THF, 2) 30percent aq. H2O2, 3N aq. NaOH, NaHSO3

2: pyridinium chlorochromate, Celite / CH₂Cl₂ / 4 h / Ambient temperature

3: NaHCO₃, 3-chloroperbenzoic acid / CH₂Cl₂ / 18 h / 4 °C

4: methanol / Heating

5: PPh₃, diethyl azodicarboxylate / tetrahydrofuran / 3 h / Ambient temperature

With sodium hydroxide; borane-THF; Celite; dihydrogen peroxide; sodium hydrogencarbonate; 2,6,6-trimethylbicyclo[3.1.1]hept-2-ene; sodium hydrogensulfite; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; pyridinium chlorochromate; diethylazodicarboxylate; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1002/hlca.19930760207