methyl 4,6-O-benzylidene-2-deoxy-2-(2-propenyl)-α-D-allohexopyranoside

Base Information

• Chemical Name: methyl 4,6-O-benzylidene-2-deoxy-2-(2-propenyl)-α-D-allohexopyranoside
• CAS No.: 126108-10-9
• Molecular Formula: C₁₇H₂₂O₅
• Molecular Weight: 306.359
• Mol file: 126108-10-9.mol

Synonyms:methyl 4,6-O-benzylidene-2-deoxy-2-(2-propenyl)-α-D-allohexopyranoside

Chemical Property of methyl 4,6-O-benzylidene-2-deoxy-2-(2-propenyl)-α-D-allohexopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 4,6-O-benzylidene-2-deoxy-2-(2-propenyl)-α-D-allohexopyranoside

There total 6 articles about methyl 4,6-O-benzylidene-2-deoxy-2-(2-propenyl)-α-D-allohexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

methyl 2,3-anhydro-4,6-benzylidene-α-D-allopyranoside (66537-92-6) → methyl 4,6-O-benzylidene-2-deoxy-2-(2-propenyl)-α-D-allohexopyranoside (126108-10-9)

Guidance literature:

With allylmagnesium bromide; In tetrahydrofuran; for 2h;

DOI:10.1071/CH9901681

Reference yield: 86.0%

allylmagnesium bromide (2622-05-1) + methyl 2,3-anhydro-4,6-benzylidene-α-D-allopyranoside (66537-92-6) → methyl 4,6-O-benzylidene-2-deoxy-2-(2-propenyl)-α-D-allohexopyranoside (126108-10-9)

Guidance literature:

In tetrahydrofuran; for 2h; Heating;

DOI:10.1021/jo981225j

Reference yield: 29.0%

methyl 4,6-O-benzylidene-2-deoxy-2-C-propenyl-α-D-arabino-hexopyranosid-3-ulose (135759-86-3) → methyl 4,6-O-benzylidene-2-deoxy-2-(2-propenyl)-α-D-allohexopyranoside (126108-10-9)

Guidance literature:

With lithium aluminium tetrahydride;

DOI:10.1039/c39910000690

upstream raw materials:

allyltributylstanane

2-methoxy-6-phenyl-1a,2,3a,4-tetrahydrooxireno<4,5>pyrano<3,2-d><1,3>dioxin

methyl 4,6-O-benzylidene-2-deoxy-2-C-propenyl-α-D-arabino-hexopyranosid-3-ulose

allylmagnesium bromide

Downstream raw materials:

methyl 3-O-benzyl-4,6-O-benzylidene-2-deoxy-2-C-(prop-2-enyl)-α-D-altropyranoside

methyl 4,6-O-benzylidene-2-deoxy-2-C-propenyl-α-D-arabino-hexopyranosid-3-ulose

methyl 3-O-benzyl-2-deoxy-2-C-(2-methoxycarbonylethyl)-6-O-phenylsulfonyl-α-D-altropyranoside

methyl 4-O-benzoyl-3-O-t-butyldimethylsilyl-6-cyano-2,6-dideoxy-2-C-(2-methoxycarbonylethyl)-α-D-altroside