dimethyl 2-((2-phenylcyclopent-1-enyl)methyl)malonate

Base Information

Chemical Name:dimethyl 2-((2-phenylcyclopent-1-enyl)methyl)malonate
CAS No.:1380523-82-9
Molecular Formula:C₁₇H₂₀O₄
Molecular Weight:288.343
Hs Code.:

Synonyms:dimethyl 2-((2-phenylcyclopent-1-enyl)methyl)malonate

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Chemical Property of dimethyl 2-((2-phenylcyclopent-1-enyl)methyl)malonate

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Technology Process of dimethyl 2-((2-phenylcyclopent-1-enyl)methyl)malonate

There total 4 articles about dimethyl 2-((2-phenylcyclopent-1-enyl)methyl)malonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1380523-80-7
(2-phenylcyclopent-1-enyl)methanol

: 1380523-82-9
dimethyl 2-((2-phenylcyclopent-1-enyl)methyl)malonate

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine; phosphorus tribromide / diethyl ether; hexane / 0.75 h / 0 °C

2: potassium carbonate / acetone / Inert atmosphere; Reflux

With pyridine; phosphorus tribromide; potassium carbonate; In diethyl ether; hexane; acetone;
DOI:10.1021/ol300625u

Reference yield:

: 65832-21-5
methyl 2-(trifluoromethylsulfonyloxy)cyclopent-1-enecarboxylate

: 1380523-82-9
dimethyl 2-((2-phenylcyclopent-1-enyl)methyl)malonate

Guidance literature:: Multi-step reaction with 4 steps

1: palladium diacetate; sodium carbonate; triphenylphosphine / ethanol; benzene / 20 h / 75 °C / Inert atmosphere

2: lithium aluminium tetrahydride / diethyl ether / 2 h / 0 °C / Inert atmosphere

3: pyridine; phosphorus tribromide / diethyl ether; hexane / 0.75 h / 0 °C

4: potassium carbonate / acetone / Inert atmosphere; Reflux

With pyridine; lithium aluminium tetrahydride; palladium diacetate; phosphorus tribromide; sodium carbonate; potassium carbonate; triphenylphosphine; In diethyl ether; ethanol; hexane; acetone; benzene;
DOI:10.1021/ol300625u

Reference yield:

: 10472-24-9,265317-94-0
methyl 2-oxocyclopentane-1-carboxylate

: 1380523-82-9
dimethyl 2-((2-phenylcyclopent-1-enyl)methyl)malonate

Guidance literature:: Multi-step reaction with 5 steps

1.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 0.17 h / -78 °C / Inert atmosphere

1.2: -78 - 20 °C / Inert atmosphere

2.1: palladium diacetate; sodium carbonate; triphenylphosphine / ethanol; benzene / 20 h / 75 °C / Inert atmosphere

3.1: lithium aluminium tetrahydride / diethyl ether / 2 h / 0 °C / Inert atmosphere

4.1: pyridine; phosphorus tribromide / diethyl ether; hexane / 0.75 h / 0 °C

5.1: potassium carbonate / acetone / Inert atmosphere; Reflux

With pyridine; lithium aluminium tetrahydride; palladium diacetate; phosphorus tribromide; sodium carbonate; potassium carbonate; N-ethyl-N,N-diisopropylamine; triphenylphosphine; In diethyl ether; ethanol; hexane; dichloromethane; acetone; benzene;
DOI:10.1021/ol300625u