p-xylylaminomethylferrocene

Base Information

• Chemical Name: p-xylylaminomethylferrocene
• CAS No.: 252651-13-1
• Molecular Formula: C₁₉H₂₁FeN
• Molecular Weight: 319.229
• Mol file: 252651-13-1.mol

Synonyms:p-xylylaminomethylferrocene

Chemical Property of p-xylylaminomethylferrocene

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of p-xylylaminomethylferrocene

There total 1 articles about p-xylylaminomethylferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

lithium aluminium tetrahydride (16853-85-3) + 4'-methylbenzyl-ferrocenylcarboxaldimine (913170-95-3) → p-xylylaminomethylferrocene (252651-13-1)

Guidance literature:

In tetrahydrofuran; (N2);reduction of imine with LiAlH4 in THF; elem. anal.;

DOI:10.1016/j.poly.2006.02.017

Reference yield: 80.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + p-xylylaminomethylferrocene (252651-13-1) → [(η5-cyclopentadienyl)Fe(η5-C5H4CH2N(CH3)CH2C6H4CH3-4)] (897921-98-1)

Guidance literature:

With sodium cyanoborohydride; In water; acetic acid; according to ref.: R.F. Borch, A.I. Hassid, J. Org. Chem. 37 (1972) 1673.; room temp.; elem. anal.;

DOI:10.1016/j.poly.2006.02.017

Reference yield: 78.0%

hydrogenchloride (7647-01-0,15364-23-5) + ammonium hexafluorophosphate + p-xylylaminomethylferrocene (252651-13-1) → [N-(xylylammonium)methylferrocene][PF6] (685869-16-3)

Guidance literature:

In hydrogenchloride; suspn. ferrocene in 6 M HCl was stirred for 12 h at room temp., solvent was evapd., residue was washed with water, suspended in acetone, NH4PF6 was added and stirred for 4 h at room temp.; soln. was filtered and evapd.; elem. anal.;

DOI:10.1021/ic050215f

upstream raw materials:

lithium aluminium tetrahydride

4'-methylbenzyl-ferrocenylcarboxaldimine

Downstream raw materials:

[N-(xylylammonium)methylferrocene][PF₆]

[N-(xylylammonium)methylferrocene][PF₆].cntnd.dibenzo[24]crown-8

[(η5-cyclopentadienyl)Fe(η5-C5H4CH2N(CH3)CH2C6H4CH3-4)]