3-phenylsulfonyl-4-phenyltricyclo[4.2.1.0^2,5]nona-3,7-diene

Base Information

• Chemical Name: 3-phenylsulfonyl-4-phenyltricyclo[4.2.1.0^2,5]nona-3,7-diene
• CAS No.: 123500-80-1
• Molecular Formula: C₂₁H₁₈O₂S
• Molecular Weight: 334.439
• Mol file: 123500-80-1.mol

Synonyms:3-phenylsulfonyl-4-phenyltricyclo[4.2.1.0^2,5]nona-3,7-diene

Chemical Property of 3-phenylsulfonyl-4-phenyltricyclo[4.2.1.0^2,5]nona-3,7-diene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-phenylsulfonyl-4-phenyltricyclo[4.2.1.0^2,5]nona-3,7-diene

There total 9 articles about 3-phenylsulfonyl-4-phenyltricyclo[4.2.1.0^2,5]nona-3,7-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

2-(benzenesulfonyl)ethynylbenzene (5324-64-1) + bicyclo[2.2.1]hepta-2,5-diene (121-46-0) → 3-phenylsulfonyl-4-phenyltricyclo[4.2.1.02,5]nona-3,7-diene (123500-80-1)

Guidance literature:

chloro(1,5-cyclooctadiene)(pentamethylcyclopentadiene)ruthenium(II); In tetrahydrofuran; at 95 ℃; for 80h;

DOI:10.1021/jo060864o

Reference yield: 85.0%

3,4-Bis-benzenesulfonyl-tricyclo[4.2.1.02,5]nona-3,7-diene (123500-77-6) + phenylmagnesium bromide → 3-phenylsulfonyl-4-phenyltricyclo[4.2.1.02,5]nona-3,7-diene (123500-80-1)

Guidance literature:

In tetrahydrofuran; diethyl ether; at -10 - 20 ℃;

Reference yield: 84.0%

2-(benzenesulfonyl)ethynylbenzene (5324-64-1) + bicyclo[2.2.1]hepta-2,5-diene (121-46-0) → 3-phenylsulfonyl-4-phenyltricyclo[4.2.1.02,5]nona-3,7-diene (123500-80-1)

Guidance literature:

With Cp*RhCl(COD); In tetrahydrofuran; at 90 ℃; for 72h;

DOI:10.1021/jo052295a

upstream raw materials:

3,4-Bis-benzenesulfonyl-tricyclo[4.2.1.0^2,5]nona-3,7-diene

3,4-bis(phenylsulphonyl)tricyclo<4.2.1.0^2,4>nona-3,7-diene

2-(benzenesulfonyl)ethynylbenzene

bicyclo[2.2.1]hepta-2,5-diene

Downstream raw materials:

2-phenyl-tricyclo<4.2.1.0^2,5>nona-3,7-diene

4-methyl-3-phenyltricyclo[4.2.1.0^2,5]nona-3,7-diene