(2,5-dimethoxyphenyl)(phenyl)selane

Base Information

• Chemical Name: (2,5-dimethoxyphenyl)(phenyl)selane
• CAS No.: 860602-99-9
• Molecular Formula: C₁₄H₁₄O₂Se
• Molecular Weight: 293.224
• Mol file: 860602-99-9.mol

Synonyms:(2,5-dimethoxyphenyl)(phenyl)selane

Chemical Property of (2,5-dimethoxyphenyl)(phenyl)selane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2,5-dimethoxyphenyl)(phenyl)selane

There total 5 articles about (2,5-dimethoxyphenyl)(phenyl)selane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

selenoanisole (4346-64-9) → (2,5-dimethoxyphenyl)(phenyl)selane (860602-99-9)

Guidance literature:

Multi-step reaction with 3 steps

1.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 0 - 20 °C

2.1: dichloromethane / -35 °C / Inert atmosphere

3.1: dichloromethane / 1.75 h / -35 - 20 °C / Inert atmosphere

3.2: 11 h / 0 °C / Inert atmosphere

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane;

DOI:10.1016/j.tetlet.2018.07.005

Reference yield:

C8H8F3O3SSe(1+)*CF3O3S(1-) + 1,4-dimethoxybezene (150-78-7) → (2,5-dimethoxyphenyl)(phenyl)selane (860602-99-9)

Guidance literature:

C₈H₈F₃O₃SSe⁽¹⁺⁾*CF₃O₃S^(1-); 1,4-dimethoxybezene; In dichloromethane; at -35 - 20 ℃; for 1.75h; Inert atmosphere;

With diisopropylamine; In dichloromethane; at 0 ℃; for 11h; Inert atmosphere;

DOI:10.1016/j.tetlet.2018.07.005

Reference yield:

diphenyl diselenide (1666-13-3) → (2,5-dimethoxyphenyl)(phenyl)selane (860602-99-9)

Guidance literature:

Multi-step reaction with 4 steps

1.1: sodium tetrahydroborate / ethanol / 0.5 h / 25 °C

1.2: 25 °C

2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / 0 - 20 °C

3.1: dichloromethane / -35 °C / Inert atmosphere

4.1: dichloromethane / 1.75 h / -35 - 20 °C / Inert atmosphere

4.2: 11 h / 0 °C / Inert atmosphere

With sodium tetrahydroborate; 3-chloro-benzenecarboperoxoic acid; In ethanol; dichloromethane;

DOI:10.1016/j.tetlet.2018.07.005

upstream raw materials:

sodium phenylselenide

1,4-dimethoxybezene

diphenyl diselenide

selenoanisole