(+)-MOD-DIOP

Base Information

Chemical Name:(+)-MOD-DIOP
CAS No.:122977-44-0
Molecular Formula:C₄₃H₅₆O₆P₂
Molecular Weight:730.862
Hs Code.:
Mol file:122977-44-0.mol

Synonyms:Phosphine,[(2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene)]bis[bis(4-methoxy-3,5-dimethylphenyl)-,(4R-trans)-; Phosphine,[[(4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-diyl]bis(methylene)]bis[bis(4-methoxy-3,5-dimethylphenyl)-(9CI); (+)-MOD-DIOP; (R,R)-MOD-DIOP

Suppliers and Price of (+)-MOD-DIOP

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of (+)-MOD-DIOP

Chemical Property:

PSA：0.00000
LogP:0.00000

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

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Technology Process of (+)-MOD-DIOP

There total 2 articles about (+)-MOD-DIOP which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 122708-97-8
bis(4-methoxy-3,5-dimethylphenyl)-phosphine

: 37002-45-2
(4S,5S)-2,2-dimethyl-4,5-bis(p-toluenesulfonyloxymethyl)-1,3-dioxolan

: 127797-02-8,122977-44-0
(4R-trans)-<(2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene)>bis

Guidance literature:: With n-butyllithium; In tetrahydrofuran; at -30 ℃;
DOI:10.1016/S0040-4039(01)80296-3

Reference yield:

: 127797-02-8,122977-44-0
(4R-trans)-<(2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene)>bis

Guidance literature:

Reference yield: 44.0%

: 127797-02-8,122977-44-0
(4R-trans)-<(2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene)>bis

: (4R,5R)-4-{[bis(4-methoxy-3,5-dimethylphenyl)phosphino]methyl}-5-{[bis(4-methoxy-3,5-dimethylphenyl)phosphoryl]methyl}-2,2-dimethyl-1,3-dioxolane borane complex

Guidance literature:: (4R-trans)-<(2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene)>bis; With borane-THF; In tetrahydrofuran; at -78 ℃; for 1h;

With dihydrogen peroxide; In ethyl acetate; at 0 ℃; for 0.5h; Further stages.;
DOI:10.1055/s-2006-950315