(2'R)-1D-3,6-di-O-benzyl-4,5-bis-O-[di(benzyloxy)phosphoryl]-1,2-O-{2'-[di(benzyloxy)phosphoryloxy]propane-1',3'-diyl}-myo-inositol

Base Information

Chemical Name:(2'R)-1D-3,6-di-O-benzyl-4,5-bis-O-[di(benzyloxy)phosphoryl]-1,2-O-{2'-[di(benzyloxy)phosphoryloxy]propane-1',3'-diyl}-myo-inositol
CAS No.:221462-14-2
Molecular Formula:C₆₅H₆₇O₁₆P₃
Molecular Weight:1197.16
Hs Code.:

Synonyms:(2'R)-1D-3,6-di-O-benzyl-4,5-bis-O-[di(benzyloxy)phosphoryl]-1,2-O-{2'-[di(benzyloxy)phosphoryloxy]propane-1',3'-diyl}-myo-inositol

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Chemical Property of (2'R)-1D-3,6-di-O-benzyl-4,5-bis-O-[di(benzyloxy)phosphoryl]-1,2-O-{2'-[di(benzyloxy)phosphoryloxy]propane-1',3'-diyl}-myo-inositol

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Technology Process of (2'R)-1D-3,6-di-O-benzyl-4,5-bis-O-[di(benzyloxy)phosphoryl]-1,2-O-{2'-[di(benzyloxy)phosphoryloxy]propane-1',3'-diyl}-myo-inositol

There total 8 articles about (2'R)-1D-3,6-di-O-benzyl-4,5-bis-O-[di(benzyloxy)phosphoryl]-1,2-O-{2'-[di(benzyloxy)phosphoryloxy]propane-1',3'-diyl}-myo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: Phosphorous acid dibenzyl ester (3R,5aR,6S,7R,8R,9S,9aS)-6,9-bis-benzyloxy-7,8-bis-(bis-benzyloxy-phosphanyloxy)-octahydro-benzo[b][1,4]dioxepin-3-yl ester

: 221462-14-2
(2'R)-1D-3,6-di-O-benzyl-4,5-bis-O-[di(benzyloxy)phosphoryl]-1,2-O-{2'-[di(benzyloxy)phosphoryloxy]propane-1',3'-diyl}-myo-inositol

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -78 ℃; Yield given; to rt;
DOI:10.1016/S0040-4039(99)00174-4

Reference yield:

: 221462-15-3
(2'S,3'S)-1D-3,6-di-O-benzyl-4,5-O-(2',3'-dimethoxybutane-2',3'-diyl)-myo-inositol

: 221462-14-2
(2'R)-1D-3,6-di-O-benzyl-4,5-bis-O-[di(benzyloxy)phosphoryl]-1,2-O-{2'-[di(benzyloxy)phosphoryloxy]propane-1',3'-diyl}-myo-inositol

Guidance literature:: Multi-step reaction with 6 steps

1.1: NaH / dimethylformamide / 0.5 h / 20 °C

1.2: 84 percent / dimethylformamide / 1 h

2.1: 82 percent / NaIO₄; aq. RuCl₃ / ethyl acetate; acetonitrile / 1.5 h / 20 °C

3.1: 21 percent / NaBH₄ / methanol / 0 - 20 °C

4.1: 83 percent / 95percent aq. TFA / CH₂Cl₂ / 0.25 h / 20 °C

5.1: 1H-tetrazole / CH₂Cl₂ / 0.33 h / 20 °C

5.2: CH₂Cl₂ / 1 h / 20 °C

6.1: m-CPBA / CH₂Cl₂ / -78 - 20 °C

With 1H-tetrazole; ruthenium trichloride; sodium tetrahydroborate; sodium periodate; sodium hydride; 3-chloro-benzenecarboperoxoic acid; In methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jm0005499

Reference yield:

: 221462-09-5
(2'S,3'S)-1D-3,6-di-O-benzyl-4,5-(2',3'-dimethoxybutane-2',3'-diyl)-1,2-O-[(2''-methylene)propane-1'',3''-diyl]-myo-inositol

: 221462-14-2
(2'R)-1D-3,6-di-O-benzyl-4,5-bis-O-[di(benzyloxy)phosphoryl]-1,2-O-{2'-[di(benzyloxy)phosphoryloxy]propane-1',3'-diyl}-myo-inositol

Guidance literature:: Multi-step reaction with 5 steps

1.1: 82 percent / NaIO₄; aq. RuCl₃ / ethyl acetate; acetonitrile / 1.5 h / 20 °C

2.1: 21 percent / NaBH₄ / methanol / 0 - 20 °C

3.1: 83 percent / 95percent aq. TFA / CH₂Cl₂ / 0.25 h / 20 °C

4.1: 1H-tetrazole / CH₂Cl₂ / 0.33 h / 20 °C

4.2: CH₂Cl₂ / 1 h / 20 °C

5.1: m-CPBA / CH₂Cl₂ / -78 - 20 °C

With 1H-tetrazole; ruthenium trichloride; sodium tetrahydroborate; sodium periodate; 3-chloro-benzenecarboperoxoic acid; In methanol; dichloromethane; ethyl acetate; acetonitrile;
DOI:10.1021/jm0005499