(1'R,2R)-dimethyl{[2-(4'-methylenecyclohex-2'-en-1'-yl)propyl]oxy}(1,1,2-trimethylpropyl)silane

Base Information

Chemical Name:(1'R,2R)-dimethyl{[2-(4'-methylenecyclohex-2'-en-1'-yl)propyl]oxy}(1,1,2-trimethylpropyl)silane
CAS No.:252289-49-9
Molecular Formula:C₁₈H₃₄OSi
Molecular Weight:294.553
Hs Code.:

Synonyms:(1'R,2R)-dimethyl{[2-(4'-methylenecyclohex-2'-en-1'-yl)propyl]oxy}(1,1,2-trimethylpropyl)silane

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Chemical Property of (1'R,2R)-dimethyl{[2-(4'-methylenecyclohex-2'-en-1'-yl)propyl]oxy}(1,1,2-trimethylpropyl)silane

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Technology Process of (1'R,2R)-dimethyl{[2-(4'-methylenecyclohex-2'-en-1'-yl)propyl]oxy}(1,1,2-trimethylpropyl)silane

There total 17 articles about (1'R,2R)-dimethyl{[2-(4'-methylenecyclohex-2'-en-1'-yl)propyl]oxy}(1,1,2-trimethylpropyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 252289-48-8
(1S,1'R,2S,3R)-3-{2'-{[dimethyl(1,1,2-trimethylpropyl)silyl]oxy}-1'-methylethyl}-6-methylenecyclohexane-1,2-diyl bis(methanesulfonate)

: 252289-49-9
(1'R,2R)-dimethyl{[2-(4'-methylenecyclohex-2'-en-1'-yl)propyl]oxy}(1,1,2-trimethylpropyl)silane

Guidance literature:: With pyridine; sodium iodide; In acetone; for 1h; Heating;
DOI:10.1002/(SICI)1522-2675(19991006)82:10<1610::AID-HLCA1610>3.0.CO;2-T

Reference yield: 40.0%

: 252289-33-1
(1S,1'R,2R,3S)-3-{2'-{[dimethyl(1,1,2-trimethylpropyl)silyl]oxy}-1'-methylpropyl}-6-methylenecyclohexane-1,2-diyl carbonothioate

: 252289-49-9
(1'R,2R)-dimethyl{[2-(4'-methylenecyclohex-2'-en-1'-yl)propyl]oxy}(1,1,2-trimethylpropyl)silane

Guidance literature:: With maleic anhydride; phosphorous acid trimethyl ester; In benzene; for 24h; Heating;
DOI:10.1002/(SICI)1522-2675(19991006)82:10<1610::AID-HLCA1610>3.0.CO;2-T

Reference yield:

: 13834-07-6
(1R,3R,4S,8R)-9-hydroxy-p-menthol

: 252289-49-9
(1'R,2R)-dimethyl{[2-(4'-methylenecyclohex-2'-en-1'-yl)propyl]oxy}(1,1,2-trimethylpropyl)silane

Guidance literature:: Multi-step reaction with 11 steps

1: 91 percent / 1H-imidazole / dimethylformamide / 15 h / 0 - 20 °C

2: 62 percent / (COCl)2; DMSO; Et₃N / CH₂Cl₂ / 3 h / -79 °C

3: 100 percent / BuLi; (i-Pr)2NH / hexane; tetrahydrofuran / 1 h / -78 °C

4: N-bromosuccinimide / tetrahydrofuran / 2 h / 0 °C

5: 74 percent / 2,4,6-trimethyl-pyridine / 1 h / 145 - 150 °C

6: 55 percent / CeCl₃*7H₂O; NaBH₄ / methanol / 1 h / 0 - 20 °C

7: 99 percent / VO(acac)2; t-BuOOH / benzene; CH₂Cl₂ / 2 h / 0 - 5 °C

8: 100 percent / Et₃N / tetrahydrofuran / 24 h / 0 - 20 °C

9: 95 percent / LiNEt₂ / tetrahydrofuran / 2 h / Heating

10: 98 percent / pyridine / benzene / 2 h / -5 - 20 °C

11: 40 percent / P(OMe)3; maleinic anhydride / benzene / 24 h / Heating

With pyridine; 1H-imidazole; tert.-butylhydroperoxide; sodium tetrahydroborate; N-Bromosuccinimide; n-butyllithium; cerium(III) chloride; oxalyl dichloride; bis(acetylacetonate)oxovanadium; lithium diethylamide; maleic anhydride; dimethyl sulfoxide; triethylamine; diisopropylamine; phosphorous acid trimethyl ester; In tetrahydrofuran; 2,4,6-trimethyl-pyridine; methanol; hexane; dichloromethane; N,N-dimethyl-formamide; benzene; 1: Substitution / 2: Oxidation / 3: Etherification / 4: Bromination / 5: Dehydrobromination / 6: Reduction / 7: Epoxidation / 8: Substitution / 9: Rearrangement / 10: Acylation / 11: Elimination;
DOI:10.1002/(SICI)1522-2675(19991006)82:10<1610::AID-HLCA1610>3.0.CO;2-T