4-trifluoromethanesulfonyloxy-benzoic acid tert-butyl ester

Base Information

• Chemical Name: 4-trifluoromethanesulfonyloxy-benzoic acid tert-butyl ester
• CAS No.: 247042-60-0
• Molecular Formula: C₁₂H₁₃F₃O₅S
• Molecular Weight: 326.293
• Mol file: 247042-60-0.mol

Synonyms:4-trifluoromethanesulfonyloxy-benzoic acid tert-butyl ester

Chemical Property of 4-trifluoromethanesulfonyloxy-benzoic acid tert-butyl ester

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 4-trifluoromethanesulfonyloxy-benzoic acid tert-butyl ester

There total 1 articles about 4-trifluoromethanesulfonyloxy-benzoic acid tert-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

trifluoromethylsulfonic anhydride (358-23-6) + tert-butyl 4-hydroxybenzoate (25804-49-3) → 4-trifluoromethanesulfonyloxy-benzoic acid tert-butyl ester (247042-60-0)

Guidance literature:

With 2,6-dimethylpyridine; In dichloromethane; at 20 ℃; for 16h;

DOI:10.1021/ja071268u

Reference yield: 91.0%

1,3-diphenylisobenzofuran (5471-63-6) + 4-trifluoromethanesulfonyloxy-benzoic acid tert-butyl ester (247042-60-0) → tert-butyl 9,10-diphenyl-9,10-epoxy-2-anthracenecarboxylate (1006715-08-7)

Guidance literature:

With bis(2,2,6,6-tetramethylpiperidin-1-yl)magnesium-bis(lithium chloride) complex; In tetrahydrofuran; at -78 - 0 ℃; for 12h; Inert atmosphere;

DOI:10.1055/s-0036-1591510

Reference yield: 81.0%

piperidine (110-89-4) + 4-trifluoromethanesulfonyloxy-benzoic acid tert-butyl ester (247042-60-0) → tert-butyl 4-piperidin-1-yl-benzoate

Guidance literature:

at 110 ℃; for 7h;

DOI:10.1055/s-1999-2886

upstream raw materials:

trifluoromethylsulfonic anhydride

tert-butyl 4-hydroxybenzoate

Downstream raw materials:

tert-butyl 9,10-diphenyl-9,10-epoxy-2-anthracenecarboxylate