beta-D-Allopyranose, 1,6:2,3-dianhydro-4-O-2-propenyl- (9CI)

Base Information

Chemical Name:beta-D-Allopyranose, 1,6:2,3-dianhydro-4-O-2-propenyl- (9CI)
CAS No.:123823-20-1
Molecular Formula:C₉H₁₂O₄
Molecular Weight:184.192
Hs Code.:
Mol file:123823-20-1.mol

Synonyms:b-D-Allopyranose,1,6:2,3-dianhydro-4-O-2-propenyl- (9CI);3,8,9-Trioxatricyclo[4.2.1.02,4]nonane, b-D-allopyranose deriv.

Suppliers and Price of beta-D-Allopyranose, 1,6:2,3-dianhydro-4-O-2-propenyl- (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of beta-D-Allopyranose, 1,6:2,3-dianhydro-4-O-2-propenyl- (9CI)

Chemical Property:

Boiling Point:None °C
PSA：40.22000
LogP:0.08010

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of beta-D-Allopyranose, 1,6:2,3-dianhydro-4-O-2-propenyl- (9CI)

There total 3 articles about beta-D-Allopyranose, 1,6:2,3-dianhydro-4-O-2-propenyl- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 123823-19-8
4-O-Allyl-1,6-anhydro-3-O-methanesulfonyl-2-O-p-toluenesulfonyl-β-D-glucopyranose

: 123823-20-1
4-O-Allyl-1,6:2,3-dianhydro-D-allopyranose

Guidance literature:: With sodium methylate; In methanol; dichloromethane; at 20 ℃; for 20h;
DOI:10.1016/S0008-6215(00)90496-8

Reference yield:

: 39697-97-7
4-O-Allyl-1,6-anhydro-2-O-tosyl-β-D-glucopyranose

: 123823-20-1
4-O-Allyl-1,6:2,3-dianhydro-D-allopyranose

Guidance literature:: Multi-step reaction with 2 steps

1: 75 percent / Et₃N / CH₂Cl₂ / 0.33 h / -15 °C

2: 90 percent / 2M NaOMe / CH₂Cl₂; methanol / 20 h / 20 °C

With sodium methylate; triethylamine; In methanol; dichloromethane;
DOI:10.1016/S0008-6215(00)90496-8