[closo-3-triphenylphosphine-3,3-nitrato-3,1,2-RhC₂B₉H₁₁]

Base Information

Chemical Name:[closo-3-triphenylphosphine-3,3-nitrato-3,1,2-RhC₂B₉H₁₁]
CAS No.:82807-97-4
Molecular Formula:C₂₀H₂₆B₉NO₃PRh
Molecular Weight:559.61
Hs Code.:

[closo-3-triphenylphosphine-3,3-nitrato-3,1,2-RhC<sub>2</sub>B<sub>9</sub>H<sub>11</sub>]

Synonyms:[closo-3-triphenylphosphine-3,3-nitrato-3,1,2-RhC₂B₉H₁₁]

Suppliers and Price of [closo-3-triphenylphosphine-3,3-nitrato-3,1,2-RhC₂B₉H₁₁]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of [closo-3-triphenylphosphine-3,3-nitrato-3,1,2-RhC₂B₉H₁₁]

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of [closo-3-triphenylphosphine-3,3-nitrato-3,1,2-RhC₂B₉H₁₁]

There total 3 articles about [closo-3-triphenylphosphine-3,3-nitrato-3,1,2-RhC₂B₉H₁₁] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: [closo-Rh(triphenylphosphine)(C₂B₉H₁₁)2]

: 82807-97-4
[closo-3-triphenylphosphine-3,3-nitrato-3,1,2-RhC₂B₉H₁₁]

Guidance literature:: With HNO₃; In dichloromethane; under Ar, 70% HNO3 added to soln. of Rh complex in CH2Cl2, mixt. stirred for 10 min at room temp.; heptane added, CH2Cl2 removed in vac., filtered;

Reference yield: 72.0%

: 53687-46-0
closo-3,3-(PPh₃)2-3-H-3,1,2-RhC₂B₉H₁₁

: 82807-97-4
[closo-3-triphenylphosphine-3,3-nitrato-3,1,2-RhC₂B₉H₁₁]

Guidance literature:: With HNO₃; In dichloromethane; soln. of Rh complex in CH2Cl2 treated in air with 70% HNO3, red mixt. stirred ar room temp. for 30 min, soln. evapd. to dryness, residue chromd., treated with 70% HNO3 with stirring for 10 min; added heptane, CH2Cl2 removed in vac., filtered;

Reference yield: 34.0%

: 53687-46-0
closo-3,3-(PPh₃)2-3-H-3,1,2-RhC₂B₉H₁₁

: 10544-72-6
dinitrogen tetraoxide

: 82807-97-4
[closo-3-triphenylphosphine-3,3-nitrato-3,1,2-RhC₂B₉H₁₁]

Guidance literature:: With NO₂; In benzene; under Ar, gentle stream of NO2/N2O4 mixt. bubbled through stirred suspn. of Rh complex in benzene at room temp. for 15 min, stirred for further5 min; evapd. to dryness in vac., chromd., treated with hexane, evapd., added hexane, allowed stand overnight, filtered;