6-Oxabicyclo[3.1.0]hex-3-en-2-one, 1-(methoxymethyl)-, (1R)- (9CI)

Base Information

Chemical Name:6-Oxabicyclo[3.1.0]hex-3-en-2-one, 1-(methoxymethyl)-, (1R)- (9CI)
CAS No.:130195-91-4
Molecular Formula:C₇H₈O₃
Molecular Weight:140.139
Hs Code.:
Mol file:130195-91-4.mol

Synonyms:6-Oxabicyclo[3.1.0]hex-3-en-2-one, 1-(methoxymethyl)-, (1R)- (9CI)

Suppliers and Price of 6-Oxabicyclo[3.1.0]hex-3-en-2-one, 1-(methoxymethyl)-, (1R)- (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 6-Oxabicyclo[3.1.0]hex-3-en-2-one, 1-(methoxymethyl)-, (1R)- (9CI)

Chemical Property:

PSA：38.83000
LogP:-0.09070

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 6-Oxabicyclo[3.1.0]hex-3-en-2-one, 1-(methoxymethyl)-, (1R)- (9CI)

There total 10 articles about 6-Oxabicyclo[3.1.0]hex-3-en-2-one, 1-(methoxymethyl)-, (1R)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 112698-62-1,130790-88-4
(-)-exo-4,5-Epoxy-endo-4-methoxymethyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-8-en-3-one

: 112698-65-4,129076-44-4,130195-91-4
(+)-4,5-Epoxy-5-methoxymethyl-2-cyclopentenone

Guidance literature:: at 360 ℃; flash vacuum pyrolysis;
DOI:10.1016/S0040-4020(01)86766-1

Reference yield:

: 112723-14-5,130195-88-9,130195-89-0,130195-90-3
4-methoxymethyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one

: 112698-65-4,129076-44-4,130195-91-4
4,5-epoxy-5-methoxymethyl-2-cyclopentenone

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / 33percent hydrogen peroxide, 0.2 N sodium hydroxide / methanol; CH₂Cl₂; H₂O / 2 h

2: 1.5 h / 0.05 - 0.06 Torr / flash vacuum thermolysis; T₁ 90 deg C / T₂ 360 deg C

With sodium hydroxide; dihydrogen peroxide; In methanol; dichloromethane; water;
DOI:10.1016/S0040-4020(01)89180-8

Reference yield:

: 112698-71-2
5-ethoxy-4-(p-tolylsulphonyl)methyl-exo-10-oxatricyclo<5.2.1.0^2,6>deca-4,8-dien-3-one

: 112698-65-4,129076-44-4,130195-91-4
4,5-epoxy-5-methoxymethyl-2-cyclopentenone

Guidance literature:: Multi-step reaction with 4 steps

1: methanol / 0.17 h / Heating

2: DIBAL / hexane

3: H₂O₂, OH^(1-)

4: 330 °C / flash vacuum thermolysis

With hydroxide; dihydrogen peroxide; diisobutylaluminium hydride; In methanol; hexane;
DOI:10.1016/S0040-4039(00)95362-0