Oxazole, 2,2'-(1-methylethylidene)bis[4,5-dihydro-4-phenyl-, (4S,4'S)-

Base Information

Chemical Name:Oxazole, 2,2'-(1-methylethylidene)bis[4,5-dihydro-4-phenyl-, (4S,4'S)-
CAS No.:131457-46-0
Molecular Formula:C21H22 N2 O2
Molecular Weight:334.418
Hs Code.:2934999090
European Community (EC) Number:678-562-7
UNII:6Q4X8PAO1T
Nikkaji Number:J725.780E
Wikidata:Q27265321
Mol file:131457-46-0.mol

Synonyms:131457-46-0;(4S,4'S)-2,2'-(Propane-2,2-diyl)bis(4-phenyl-4,5-dihydrooxazole);(S,S)-Phbox;Ph-box, (S,S)-;Oxazole, 2,2'-(1-methylethylidene)bis[4,5-dihydro-4-phenyl-, (4S,4'S)-;(S,S)-2,2'-ISOPROPYLIDENE-BIS(4-PHENYL-2-OXAZOLINE);(S,S)-Ph-box [MI];(S,S)-2,2'-Isopropylidenebis(4-phenyl-2-oxazoline);(S,S)-2,2-Bis(4-phenyl-2-oxazolin-2-yl)propane;6Q4X8PAO1T;(4S,4S)-2,2-(Propane-2,2-diyl)bis(4-phenyl-4,5-dihydrooxazole);2,2'-(S)-Isopropylidene-bis(4-phenyl-2-oxazoline);(4S)-4-phenyl-2-[2-[(4S)-4-phenyl-4,5-dihydro-1,3-oxazol-2-yl]propan-2-yl]-4,5-dihydro-1,3-oxazole;(-)-2,2'-ISOPROPYLIDENEBIS[(4S)-4-PHENYL-2-OXAZOLINE];(4S,4'S)-2,2'-(1-Methylethylidene)bis(4,5-dihydro-4-phenyloxazole);Oxazole, 2,2'-(1-methylethylidene)bis(4,5-dihydro-4-phenyl-, (4S,4'S)-;C21H22N2O2;(-)-2,2'-Isopropylidenebis[(4S)-4-phenyl-2-oxazoline], 97%;(-)-2,2-BIS[(4S)-4-PHENYL-2-OXAZOLIN-2-YL]PROPANE;(4S)-4-phenyl-2-{2-[(4S)-4-phenyl-4,5-dihydro-1,3-oxazol-2-yl]propan-2-yl}-4,5-dihydro-1,3-oxazole;Bis(oxazoline) ligands;UNII-6Q4X8PAO1T;(S,S)-ph-box;Bis(oxazoline) ligands (S,S)-ph-box [MI];SCHEMBL917712;JTNVCJCSECAMLD-QZTJIDSGSA-N;AMY25556;BCP26530;MFCD00192245;AKOS015838408;AKOS015913345;CS-W014499;SC11775;AS-72642;I0582;T71709;J-006007;2,2'-isopropylidenebis[(4S)-4-phenyl-2-oxazoline];Q27265321;(S,S)-2,2'-(Dimethylmethylene)bis(4-phenyl-2-oxazoline);(S)-4-phenyl-2-(2-((S)-4-phenyl-4,5-dihydrooxazol-2-yl)propan-2-yl)-4,5-dihydrooxazole;2-[1-methyl-1-(4-phenyl-4,5-dihydro-1,3-oxazol-2-yl)ethyl]-4-phenyl-4,5-dihydro-1,3-oxazole

Suppliers and Price of Oxazole, 2,2'-(1-methylethylidene)bis[4,5-dihydro-4-phenyl-, (4S,4'S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(S,S)-2,2''-Isopropylidenebis(4-phenyl-2-oxazoline)
2.5mg
$ 45.00

TCI Chemical
(S,S)-2,2'-Isopropylidenebis(4-phenyl-2-oxazoline) >95.0%(GC)
1g
$ 228.00

TCI Chemical
(S,S)-2,2'-Isopropylidenebis(4-phenyl-2-oxazoline) >95.0%(GC)
250mg
$ 85.00

Strem Chemicals
(-)-2,2-Bis[(4S)-4-phenyl-2-oxazolin-2-yl]propane, 98%
250mg
$ 96.00

Strem Chemicals
(-)-2,2-Bis[(4S)-4-phenyl-2-oxazolin-2-yl]propane, 98%
1g
$ 289.00

Sigma-Aldrich
(?)-2,2′-Isopropylidenebis[(4S)-4-phenyl-2-oxazoline] pore size 1000 , 25-35μmol/g
1g
$ 276.00

Sigma-Aldrich
(?)-2,2′-Isopropylidenebis[(4S)-4-phenyl-2-oxazoline] 97%
250mg
$ 106.00

Crysdot
(4S,4'S)-2,2'-(Propane-2,2-diyl)bis(4-phenyl-4,5-dihydrooxazole) 95+%
1g
$ 368.00

ChemScene
(4S,4'S)-2,2'-(Propane-2,2-diyl)bis(4-phenyl-4,5-dihydrooxazole) ≥98.0%
1g
$ 120.00

ChemScene
(4S,4'S)-2,2'-(Propane-2,2-diyl)bis(4-phenyl-4,5-dihydrooxazole) ≥98.0%
250mg
$ 50.00

Total 33 raw suppliers

Chemical Property of Oxazole, 2,2'-(1-methylethylidene)bis[4,5-dihydro-4-phenyl-, (4S,4'S)-

Chemical Property:

Melting Point:37-41 °C(lit.)
Refractive Index:1.611
Boiling Point:193 °C0.03 mm Hg(lit.)
PKA:4.85±0.70(Predicted)
Flash Point:110 ºC
PSA：43.18000
Density:1.18g/cm³
LogP:3.22380
Storage Temp.:−20°C
XLogP3:3.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:334.168127949
Heavy Atom Count:25
Complexity:482

Purity/Quality:

98%,99%ee ^*data from raw suppliers

(S,S)-2,2''-Isopropylidenebis(4-phenyl-2-oxazoline) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 36/37/38
Safety Statements: 22-24/25

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C1=NC(CO1)C2=CC=CC=C2)C3=NC(CO3)C4=CC=CC=C4
Isomeric SMILES:CC(C)(C1=N[C@H](CO1)C2=CC=CC=C2)C3=N[C@H](CO3)C4=CC=CC=C4
Uses C2 symmetric ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.

Technology Process of Oxazole, 2,2'-(1-methylethylidene)bis[4,5-dihydro-4-phenyl-, (4S,4'S)-

There total 11 articles about Oxazole, 2,2'-(1-methylethylidene)bis[4,5-dihydro-4-phenyl-, (4S,4'S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%