D-[1-13C]THREO-PENT-2-ULOSE

Base Information

• Chemical Name: D-[1-13C]THREO-PENT-2-ULOSE
• CAS No.: 131771-46-5
• Molecular Formula: C5H10O5
• Molecular Weight: 151.14
• Mol file: 131771-46-5.mol

Synonyms:D-[1-13C]THREO-PENT-2-ULOSE;D-[1-13C]XYLULOSE

Chemical Property of D-[1-13C]THREO-PENT-2-ULOSE

Chemical Property:

• PSA: 97.99000
• LogP: -2.73810
• Storage Temp.: Refrigerator
• Solubility.: Methanol, Water

Purity/Quality:

97% ^*data from raw suppliers

D-[1-13C]Xylulose ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: D-[1-13C]Xylulose can be used through fermentation to produce ethanol. D-Xylulose can be used through fermentation to produce ethanol. This is the D-[1-13C]Xylulose labeled analog.

Technology Process of D-[1-13C]THREO-PENT-2-ULOSE

There total 13 articles about D-[1-13C]THREO-PENT-2-ULOSE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

D-Glyceraldehyde (453-17-8,367-47-5,26793-98-6) + (2,3-13C2)-D,L-Serine (131000-15-2) → keto-(1,2-13C2)-D-xylulose (131000-17-4,131771-46-5)

Guidance literature:

With thiamine monophosphate; D-amino acid oxidase; transketolase; Tris buffer; oxygen; magnesium chloride; catalase; for 12h; Ambient temperature;

DOI:10.1016/0008-6215(90)84008-I

Reference yield:

D-[1,2,3,4,5,6-13C6]glucose (101615-89-8,120388-24-1,201741-04-0,478518-62-6,478529-32-7,478529-46-3,138079-87-5,478518-58-0,478519-02-7,478518-64-8,478529-73-6,74134-89-7) → [2,3,4,5-13C4]ribose (139657-61-7,139657-63-9,178101-87-6,201741-00-6,202114-47-4,211947-12-5,213825-57-1,478506-64-8) + [U-13C5]ribulose (131771-46-5)

Guidance literature:

D-[1,2,3,4,5,6-¹³C₆]glucose; With ATP; hexokinase; glucose 6-phosphate dehydrogenase; In various solvent(s); at 37 ℃; pH=7.8;

With pentose isomerase; tris hydrochloride; NADP; In various solvent(s); at 37 ℃; for 2h; pH=7.8;

With magnesium chloride; zinc(II) chloride; alkaline phosphatase; In various solvent(s); at 37 ℃; for 4h; pH=7.9; Title compound not separated from byproducts;

DOI:10.1016/S0031-9422(98)00733-X

Reference yield:

<1-13C>D-Fructose 6-phosphate (65861-56-5) → [1-13C]-D-xylulose (131771-46-5)

Guidance literature:

With thiamine pyrophosphate; TEA buffer; Glyceraldehyde; transketolase; magnesium chloride; at 37 ℃; for 8h; pH=7.6;

DOI:10.1002/jms.147

upstream raw materials:

D-Glyceraldehyde

(2,3-13C₂)-D,L-Serine

D-[1,2,3,4,5,6-¹³C₆]glucose

<1-¹³C>D-Fructose 6-phosphate

Refernces

• 1、 Zhang, Wenhui,Serianni, Anthony S.. "Phosphate-catalyzed degradation of d-glucosone in aqueous solution is accompanied by C1-C2 transposition". experimental part. p. 11511 - 11524. Retrieved 2012/08/28.
• 2、 Demuynck, Colette,Bolte, Jean,Hecquet, Laurence,Samaki, Hamid. "Enzymes as reagents in organic chemistry: transketolase-catalyzed synthesis of D-xylulose". . p. 79 - 85. Retrieved 2007/10/02.