(+)-TRANS-MYRTANOL

Base Information

• Chemical Name: (+)-TRANS-MYRTANOL
• CAS No.: 132203-71-5
• Molecular Formula: C₁₀H₁₈O
• Molecular Weight: 154.252
• Mol file: 132203-71-5.mol

Synonyms:(1R,2R)-10-PINANOL;(1R,2R)-6,6-DIMETHYLBICYCLO[3.1.1]HEPTANE-2-METHANOL;(+)-TRANS-MYRTANOL;(+)-TRANS-MYRTANOL, TERPENE STANDARD;MYRTANOL, -(-)-trans-(SG);(1R,2R)-10-Pinanol, (1R,2R)-6,6-Dimethylbicyclo[3.1.1]heptane-2-methanol

Chemical Property of (+)-TRANS-MYRTANOL

Chemical Property:

• Vapor Pressure: 0.0249mmHg at 25°C
• Refractive Index: n20/D 1.488
• Boiling Point: 219.5°C at 760 mmHg
• PKA: 14.99±0.10(Predicted)
• Flash Point: 86 °C
• PSA: 20.23000
• Density: 0.973 g/mL at 20 °C(lit.)
• LogP: 2.05100
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

(+)-TRANS-MYRTANOL 95.00% ^*data from reagent suppliers

Safty Information:

• Safety Statements: 23-24/25

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (+)-TRANS-MYRTANOL

There total 22 articles about (+)-TRANS-MYRTANOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

potassium (((1S*,2R*,5S*)-6,6-dimethylbicyclo[3.1.1]heptan-2-yl)methyl)trifluoroborate → ((1S*,2R*,5S*)-6,6-dimethylbicyclo[3.1.1]heptan-2-yl)methanol (473-01-8,514-99-8,15358-91-5,15358-92-6,51152-12-6,53369-17-8,73136-30-8,132203-71-5)

Guidance literature:

With rose bengal; triethylamine; In ethanol; at 25 ℃; for 12h; Schlenk technique; Irradiation;

DOI:10.1021/acs.orglett.8b02095

Reference yield: 93.0%

(1R,5R)-(+)-β-pinene (127-91-3,25719-60-2) → cis-myrtanol (473-01-8,514-99-8,15358-91-5,15358-92-6,51152-12-6,53369-17-8,73136-30-8,132203-71-5)

Guidance literature:

With C₁₁H₇F₁₇S⁽¹⁺⁾B^(1-)H₃; 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl methyl sulfide; In FC-72; dichloromethane;

Reference yield: 85.0%

(1R/S,5R/S)-6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane (127-91-3,25719-60-2) → ((1S*,2R*,5S*)-6,6-dimethylbicyclo[3.1.1]heptan-2-yl)methanol (473-01-8,514-99-8,15358-91-5,15358-92-6,51152-12-6,53369-17-8,73136-30-8,132203-71-5)

Guidance literature:

With sodium tetrahydroborate; titanium tetrachloride; In 1,2-dimethoxyethane; Ambient temperature;

DOI:10.1039/c39800000414

upstream raw materials:

myrtenal

myrtenol

2-chloromethyl-6,6-dimethylbicyclo[3.1.1]heptane

(1R,5R)-(+)-β-pinene

Downstream raw materials:

cis-myrtanal

(+/-)-Myrtanal

(+/-)-Isomyrtanal

(1R)-10-Acetoxy-cis-pinan

Refernces

• 1、 Souto, José A.,Stockman, Robert A.,Ley, Steven V.. "Development of a flow method for the hydroboration/oxidation of olefins". . p. 3871 - 3877. Retrieved 2015/03/30.
• 2、 Revell, Jefferson D.,Doerner, Barbara,White, Peter D.,Ganesan. "PS-COD and PS-9-BBN: Polymer-supported reagents for solution-phase parallel synthesis". . p. 831 - 833. Retrieved 2007/10/03.