Magnesium bis(trifluoromethylsulfonyl)imide

Base Information

• Chemical Name: Magnesium bis(trifluoromethylsulfonyl)imide
• CAS No.: 133395-16-1
• Molecular Formula: CH2F3MgNO2S
• Molecular Weight: 584.602
• European Community (EC) Number: 634-340-1
• Nikkaji Number: J836.452D
• Mol file: 133395-16-1.mol

Synonyms:133395-16-1;Magnesium bis(trifluoromethylsulfonyl)imide;MFCD14156020;Magnesium triflimide;Magnesium(II) Bis(trifluoromethanesulfonyl)imide 99.5%;Magnesium(II) Bis(trifluoromethanesulfonyl)imide;Magnesium(II) Triflimide;DMFBPGIDUUNBRU-UHFFFAOYSA-N;magnesium bistrifluoromethanesulfonimide;SY071697;M2861;Magnesium(II) Bis(trifluoromethylsulfonyl)imide;Bis(trifluoromethanesulfonyl)imide Magnesium(II) Salt

Chemical Property of Magnesium bis(trifluoromethylsulfonyl)imide

Chemical Property:

• Melting Point: >200℃
• PSA: 85.04000
• LogP: 3.22090
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Sensitive.: Moisture Sensitive
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 22
• Rotatable Bond Count: 4
• Exact Mass: 583.8196293
• Heavy Atom Count: 31
• Complexity: 374

Purity/Quality:

98%,99%, ^*data from raw suppliers

MagnesiumBis(trifluoromethaneSulfone)imide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 22-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F.C(F)(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F.[Mg+2]
• Uses: Magnesium bis(trifluoromethylsulfonyl)imide is a strong Lewis acid and used as a catalyst in organic synthesis. It is an electrolyte, which shows high anodic stability used in rechargeable magnesium batteries.

Technology Process of Magnesium bis(trifluoromethylsulfonyl)imide

There total 1 articles about Magnesium bis(trifluoromethylsulfonyl)imide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C2HF6NO4S2*C9H12O (1174719-19-7) → 1-(ethoxymethyl)benzene (539-30-0) + magnesium bis(trifluoromethane solfonyl)imide (133395-16-1)

Guidance literature:

With magnesium carbonate; In ethanol; at 20 ℃; Inert atmosphere;

DOI:10.1016/j.tet.2009.04.068

Reference yield: 76.0%

bis[(6-dicyclohexylphosphino-2-pyridyl)methyl][(2-pyridyl)methyl]amine + magnesium bis(trifluoromethane solfonyl)imide (133395-16-1) → C42H60MgN4P2(2+)*2C2F6NO4S2(1-)

Guidance literature:

In diethyl ether; at 42 ℃; for 72h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1021/acs.organomet.1c00449

Reference yield: 63.0%

acetylacetonatodicarbonylrhodium(l) + bis[(6-dicyclohexylphosphino-2-pyridyl)methyl][(2-pyridyl)methyl]amine + magnesium bis(trifluoromethane solfonyl)imide (133395-16-1) → C44H60N4O2P2Rh2(2+)*2C2F6NO4S2(1-)

Guidance literature:

In dichloromethane; at 40 ℃; for 72h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1021/acs.organomet.1c00449

upstream raw materials:

C₂HF₆NO₄S₂*C₉H₁₂O

Refernces