Hexyl methyl methylphosphonate

Base Information

• Chemical Name: Hexyl methyl methylphosphonate
• CAS No.: 133736-02-4
• Molecular Formula: C8H19O3P
• Molecular Weight: 0
• Mol file: 133736-02-4.mol

Synonyms:Hexyl methyl methylphosphonate

Chemical Property of Hexyl methyl methylphosphonate

Chemical Property:

• PSA: 45.34000
• LogP: 3.05260

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Hexyl methyl methylphosphonate

There total 5 articles about Hexyl methyl methylphosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

sodium methyl methanephosphonate (73750-69-3) + 1-Iodohexane (638-45-9) → n-hexyl methyl methylphosphonate (133736-02-4)

Guidance literature:

Reference yield: 16.0%

dimethyl methane phosphonate (756-79-6) + hexan-1-ol (111-27-3) → Dihexyl methylphosphonate (77304-63-3) + n-hexyl methyl methylphosphonate (133736-02-4)

Guidance literature:

With tetraethylammonium perchlorate; In acetonitrile; at -20 ℃; cathodic electrolysis (1.01 F/mole, vitreous carbon electrode);

DOI:10.1007/BF00959658

Reference yield:

n-hexyl methylphosphonic acid (148456-69-3) + diazomethyl-trimethyl-silane (18107-18-1) → n-hexyl methyl methylphosphonate (133736-02-4)

Guidance literature:

With methanol; In tetrahydrofuran; benzene; at 20 ℃;

DOI:10.1080/10426500490459632

upstream raw materials:

sodium methyl methanephosphonate

1-Iodohexane

dimethyl methane phosphonate

hexan-1-ol

Refernces

• 1、 Ahlmark, Marko J.,Vepsaelaeinen, Jouko J.. "Strategies for the selective synthesis of monosubstituted (Dichloromethylene)bisphosphonate esters". . p. 16153 - 16160. Retrieved 2007/10/03.
• 2、 Niyazymbetov, M. E.,Kostizella, B.,Keitel, I.,Schwartz, K. H.. "CATHODE-CATALYZED TRANSESTERIFICATION OF ALKYLPHOSPHONATES". . p. 182 - 186. Retrieved 2007/10/02.