Bis(trimethylsilyl)methylamine

Base Information

• Chemical Name: Bis(trimethylsilyl)methylamine
• CAS No.: 134340-00-4
• Molecular Formula: C7H21NSi2
• Molecular Weight: 175.421
• Hs Code.: 2942000000
• European Community (EC) Number: 678-035-1
• DSSTox Substance ID: DTXSID80451218
• Nikkaji Number: J957.544H
• Wikidata: Q82271132
• Mol file: 134340-00-4.mol

Synonyms:Bis(trimethylsilyl)methylamine;134340-00-4;Bis(trimethylsilyl)methanamine;Methanamine, 1,1-bis(trimethylsilyl)-;B1826;SCHEMBL614476;DTXSID80451218;RTSDKFPTCHQXCH-UHFFFAOYSA-N;MFCD00671505;AKOS015839997;CS-0203996;[AMINO(TRIMETHYLSILYL)METHYL]TRIMETHYLSILANE

Chemical Property of Bis(trimethylsilyl)methylamine

Chemical Property:

• Vapor Pressure: 6.216mmHg at 25°C
• Refractive Index: n20/D 1.421(lit.)
• Boiling Point: 144-147 °C(lit.)
• PKA: 11.57±0.29(Predicted)
• Flash Point: 38.562°C
• PSA: 3.24000
• Density: 0.799 g/mL at 20 °C(lit.)
• LogP: 2.58800
• Solubility.: sol ether, alcohol, dichloromethane, and most organic solvents; hydrochloride salt sol in H2O, alcohol, DMF, DMSO.
• Water Solubility.: Decomposes
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 175.12125274
• Heavy Atom Count: 10
• Complexity: 95.8

Purity/Quality:

98% ^*data from raw suppliers

Bis(trimethylsilyl)methylamine ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 10-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)C(N)[Si](C)(C)C
• Physical properties: colorless liquid, bp 70°Cat 25 mm Hg; its hydrochloride salt, mp 191 °C.
• Uses: Methanamine, 1,1-Bis(trimethylsilyl) is reagent used for the preparation of N-bis(trimethylsilyl)methyl amines, imines, as a synthetic equivalent of N-methyl, N- (trimethylsilyl)methyl carbanion, and [N-CH] dianion synthons, as an N-protecting group.