(+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE

Base Information

• Chemical Name: (+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE
• CAS No.: 136705-62-9
• Molecular Formula: C18H36P2
• Molecular Weight: 314.43
• Mol file: 136705-62-9.mol

Synonyms:(+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE;(R,R)-ET-BPE;Bisdiethylphospholanoethane;(+)-1,2-Bis[(2R,5R)-2,5-diethylphospholano]ethane, Kanata purity;(+)-1,2-Bis((2R,5R)-2,5-diethylphospholano)ethane,98+%(R,R)-Et-BPE

Chemical Property of (+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: n20/D 1.5249
• Boiling Point: 104-106°C 0,5mm
• Flash Point: 110 °C
• PSA: 27.18000
• Density: 0.939 g/mL at 25 °C
• LogP: 6.65220
• Sensitive.: Air Sensitive

Purity/Quality:

98%,99%, ^*data from raw suppliers

(+)-1,2-Bis((2R,5R)-2,5-diethylphospholano)ethane, 98+% (R,R)-Et-BPE ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE

There total 2 articles about (+)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)ETHANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(3S,6S)-octane-3,6-diol (136705-66-3) → (+)-1,2-bis((2R,5R)-2,5-diethylphospholano)ethane (136705-62-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) SOCl₂, 2.) RuCl₃*3H₂O, NaIO₄ / 1.) CCl₄, reflux, 1.5 h, 2.) CCl₄, CH₃CN, H₂O, 25 deg C, 1 h

2: 1.) n-BuLi, 3.) n-BuLi

With ruthenium trichloride; sodium periodate; n-butyllithium; thionyl chloride;

Reference yield:

1,2-diphosphinoethane (5518-62-7) + (S,S)-octane-3,6-diol cyclic sulfate (136705-67-4) → (+)-1,2-bis((2R,5R)-2,5-diethylphospholano)ethane (136705-62-9)

Guidance literature:

With n-butyllithium; Yield given. Multistep reaction;

upstream raw materials:

1,2-diphosphinoethane

(S,S)-octane-3,6-diol cyclic sulfate

(3S,6S)-octane-3,6-diol

Refernces