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Technology Process of 1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

Base Information
  • Chemical Name:1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
  • CAS No.:136705-77-6
  • Molecular Formula:C31H48F3O3P2RhS
  • Molecular Weight:722.62
  • Hs Code.:29310099
  • European Community (EC) Number:634-363-7
  • Mol file:136705-77-6.mol
1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate

Synonyms:136705-77-6;1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate;(1Z,5Z)-cycloocta-1,5-diene;(2R,5R)-1-[2-[(2R,5R)-2,5-diethylphospholan-1-yl]phenyl]-2,5-diethylphospholane;rhodium;trifluoromethanesulfonate;(-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, 98+% (R,R)-Et-DUPHOS-Rh;XGPXBCKGQLCHDW-KYOOHHHUSA-M;MFCD00269860;J-006893;(-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate;1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulfonate

Suppliers and Price of 1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Supply Marketing:
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • Strem Chemicals
  • (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, 98+% (R,R)-Et-DUPHOS-Rh
  • 2g
  • $ 1540.00
  • Strem Chemicals
  • (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, 98+% (R,R)-Et-DUPHOS-Rh
  • 500mg
  • $ 474.00
  • Strem Chemicals
  • (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, 98+% (R,R)-Et-DUPHOS-Rh
  • 100mg
  • $ 111.00
  • Sigma-Aldrich
  • 1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
  • 50mg
  • $ 84.00
  • Sigma-Aldrich
  • 1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
  • 250mg
  • $ 329.00
  • BLDpharm
  • 1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate 98%
  • 100mg
  • $ 192.00
  • Biosynth Carbosynth
  • (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate
  • 250 mg
  • $ 550.00
  • Biosynth Carbosynth
  • (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate
  • 50 mg
  • $ 160.00
  • Biosynth Carbosynth
  • (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate
  • 25 mg
  • $ 100.00
  • Biosynth Carbosynth
  • (-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate
  • 10 mg
  • $ 50.00
Total 9 raw suppliers
Chemical Property of 1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Chemical Property:
  • PSA：92.76000 
  • LogP:10.40800 
  • Storage Temp.:Refrigerator (+4°C) 
  • Sensitive.:Air Sensitive 
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:6
  • Rotatable Bond Count:6
  • Exact Mass:722.18064
  • Heavy Atom Count:41
  • Complexity:539
Purity/Quality:

98%,99%, *data from raw suppliers

(-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate, 98+% (R,R)-Et-DUPHOS-Rh *data from reagent suppliers

Safty Information:
  • Pictogram(s):  
  • Hazard Codes:Xi 
  • Statements: 36/37/38 
  • Safety Statements: 24/25-36/37-26 
MSDS Files:
Useful:
  • Canonical SMILES:CCC1CCC(P1C2=CC=CC=C2P3C(CCC3CC)CC)CC.C1CC=CCCC=C1.C(F)(F)(F)S(=O)(=O)[O-].[Rh]
  • Isomeric SMILES:CC[C@H]1P([C@@H](CC1)CC)C2=CC=CC=C2P3[C@@H](CC[C@H]3CC)CC.C1/C=C\CC/C=C\C1.C(S(=O)(=O)[O-])(F)(F)F.[Rh]
  • Uses DuPhos and BPE Ligands: Highly Efficient Privileged LigandsCatalyst for:Stereoselective synthesis of δ-amino acid derivatives via asymmetric hydrogenation of acetylaminopentenoic acid derivativesStereoselective synthesis of manzacidins A and C via stereoselective hydrogenationStereoselective synthesis of tetracyclic core of manzamine A via Rh-catalyzed asymmetric hydrogenation, diastereoselective Diels-Alder reaction, Eschenmoser-Tanabe fragmentation, Chang′s amide formation, and Hofmann rearrangementAsymmetric preparation of chiral Cbz-aminodifluorobutyric acid Me ester and its analogsBiphasic catalytic hydrogenations in ionic liquids with addition of water as a second solventPreparation of cyclobutane-containing amino acids via asymmetric hydrogenations of cyclobutyl enamidesAsymmetric preparation of both enantiomers of (dimethoxycoumaryl)alanine as suitable fluorescent peptide labels
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