(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine

Base Information

Chemical Name:(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine
CAS No.:138517-66-5
Molecular Formula:C16H16N2
Molecular Weight:236.316
Hs Code.:2921590090
European Community (EC) Number:677-198-6
DSSTox Substance ID:DTXSID90467628
Nikkaji Number:J1.492.553H,J2.743.692G
Wikidata:Q82294667
Mol file:138517-66-5.mol

Synonyms:138517-66-5;(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine;9,10-Ethanoanthracene-11,12-diamine, 9,10-dihydro-, (11S,12S)-;(15S,16S)-tetracyclo[6.6.2.02,7.09,14]hexadeca-2,4,6,9,11,13-hexaene-15,16-diamine;D3445;SCHEMBL2481267;DTXSID90467628;MFCD09038519;MFCD09038520;AKOS027252925;CS-W010315;AS-71349;T70246;J-007152;(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine, AldrichCPR;(11R,12R)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine, >=95.0% (HPLC);(15S,16S)-tetracyclo[6.6.2.0(2),?.0?,(1)?]hexadeca-2(7),3,5,9(14),10,12-hexaene-15,16-diamine;(15S,16S)-tetracyclo[6.6.2.0?,?.0?,??]hexadeca-2(7),3,5,9(14),10,12-hexaene-15,16-diamine

Suppliers and Price of (11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine
2mg
$ 60.00

TRC
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine
10mg
$ 75.00

TCI Chemical
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine >98.0%(HPLC)(T)
1g
$ 655.00

TCI Chemical
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine >98.0%(HPLC)(T)
100mg
$ 124.00

Sigma-Aldrich
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine ≥95.0% (HPLC)
250mg
$ 111.00

Sigma-Aldrich
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine ≥95.0% (HPLC)
1g
$ 397.00

Chemenu
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine 95%
1g
$ 449.00

Biosynth Carbosynth
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine
50 mg
$ 65.00

Biosynth Carbosynth
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine
100 mg
$ 125.00

Biosynth Carbosynth
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine
250 mg
$ 200.00

Total 9 raw suppliers

Chemical Property of (11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine

Chemical Property:

Vapor Pressure:0mmHg at 25°C
Melting Point:158 °C
Refractive Index:20 ° (C=1, MeOH)
Boiling Point:396.72°C at 760 mmHg
PKA:9.38±0.40(Predicted)
Flash Point:231.6°C
PSA：52.04000
Density:1.195g/cm³
LogP:3.33260
Storage Temp.:under inert gas (nitrogen or Argon) at 2–8 °C
XLogP3:1.5
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:236.131348519
Heavy Atom Count:18
Complexity:273

Purity/Quality:

98%,99%, ^*data from raw suppliers

(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C2C3C(C(C(C2=C1)C4=CC=CC=C34)N)N
Isomeric SMILES:C1=CC=C2C3[C@@H]([C@H](C(C2=C1)C4=CC=CC=C34)N)N
Uses (11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine is a chiral diamine, which can be used as a reactant: To synthesize pyridine based C2-symmetrical chiral organocatalysts via palladium catalyzed coupling reaction with 2-bromo-4-(alkylamino)pyridine. To prepare porous organic imine cages by cycloimination reaction with triformylbenzene. To synthesize Ga/Yb-Schiff base complex, which is utilized as a catalyst for the asymmetric synthesis of 5-amino-2-(hydroxyalkyl)oxazoles by enantioselective α-addition of α-isocyano amides to aldehydes.

Technology Process of (11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine

There total 9 articles about (11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: (11S,12S)-11,12-diamino-9,10-dihydro-9,10-ethanoanthracene (R)-mandelate monoammonium salt

: 138517-66-5
(9R,10R,11S,12S)-9,10-dihydro-9,10-ethanoanthracene-11,12-diamine

Guidance literature:: With sodium hydroxide; In dichloromethane; water; at 20 - 25 ℃; for 1h; enantioselective reaction;
DOI:10.1021/acs.orglett.6b00224