(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine)

Base Information

• Chemical Name: (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine)
• CAS No.: 145214-59-1
• Molecular Formula: C₃₀H₂₄O₆P₂
• Molecular Weight: 542.464
• Hs Code.: 29321900
• European Community (EC) Number: 814-046-1,816-313-8
• DSSTox Substance ID: DTXSID80571223
• Nikkaji Number: J2.864.959B,J2.995.863G
• Wikidata: Q82459255
• Mol file: 145214-59-1.mol

Synonyms:145214-57-9;145214-59-1;(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine);(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine);Phosphine, 1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-di-2-furanyl-;(R)-(+)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(S)-(-)-2,2/'-Bis(di-2-furanylphosphino)-6,6/'-dimethoxy-1,1/'-biphenyl,min.97per cent;[2-[2-[bis(furan-2-yl)phosphanyl]-6-methoxyphenyl]-3-methoxyphenyl]-bis(furan-2-yl)phosphane;MFCD09753004;(R)-(+)-2,2/'-Bis(di-2-furanylphosphino)-6,6/'-dimethoxy-1,1/'-biphenyl,min.97per cent;(S)-2-Furyl-MeOBIPHEP;SCHEMBL642670;DTXSID80571223;VFA21459;(R)-(+)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%;CS-0086650;J-008072;J-008073;(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine);(6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl)bis[di(furan-2-yl)phosphane];(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(S)-(-)-2,2'-Bis(di-2-furylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(S)-(6,6(2)-Dimethoxybiphenyl-2,2(2)-diyl)bis(di-2-furylphosphine);(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine), >=97%, optical purity ee: >=99%;(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine), >=97%, optical purity ee: >=99%

Chemical Property of (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine)

Chemical Property:

• Boiling Point: 587.5±50.0 °C(Predicted)
• PSA: 98.20000
• LogP: 5.25920
• XLogP3: 6.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 9
• Exact Mass: 542.10481248
• Heavy Atom Count: 38
• Complexity: 652

Purity/Quality:

98%,99%, ^*data from raw suppliers

(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=C(C(=CC=C1)P(C2=CC=CO2)C3=CC=CO3)C4=C(C=CC=C4P(C5=CC=CO5)C6=CC=CO6)OC
• Uses: Atropisomeric MeOBIPHEP ligands

Technology Process of (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine)

There total 1 articles about (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(R)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine oxide) (145214-56-8,145214-58-0) + water (7732-18-5) → 2,2'-bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl (145214-57-9,145214-59-1,256390-42-8)

Guidance literature:

With sodium hydroxide; tributyl-amine; trichlorosilane; In 5,5-dimethyl-1,3-cyclohexadiene; ethanol; dichloromethane;

upstream raw materials:

(R)-(6,6'-dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine oxide)

water