2,4,6-Nonatrienal, (2E,4E,6E)-

Base Information

• Chemical Name: 2,4,6-Nonatrienal, (2E,4E,6E)-
• CAS No.: 57018-53-8
• Molecular Formula: C9H12O
• Molecular Weight: 136.19
• Mol file: 57018-53-8.mol

Synonyms:2,4,6-Nonatrienal, (2E,4E,6E)-;NONA-2,4,6-TRIENAL

Chemical Property of 2,4,6-Nonatrienal, (2E,4E,6E)-

Chemical Property:

• Boiling Point: 233.5±9.0 °C(Predicted)
• PSA: 17.07000
• Density: 0.877±0.06 g/cm3(Predicted)
• LogP: 2.26390
• Storage Temp.: Amber Vial, -20°C Freezer, Under inert atmosphere
• Solubility.: Chloroform (Slightly), Ethyl Acetate (Slightly)

Purity/Quality:

99% ^*data from raw suppliers

(2E,4E,6E)-2,4,6-Nonatrienal(>90%) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: (2E,4E,6E)-2,4,6-Nonatrienal is an unsaturated aldehyde that is a natural volatile constituent of aggregation pheromones produced by male flea beetles. (2E,4E,6E)-2,4,6-Nonatrienal is also found in licorice root, one of the widely used herbs for its

Technology Process of 2,4,6-Nonatrienal, (2E,4E,6E)-

There total 12 articles about 2,4,6-Nonatrienal, (2E,4E,6E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

(E,E,E)-2,4,6-nonatrienol → (E,E,E)-2,4,6-nonatrienal (57018-53-8)

Guidance literature:

With Dess-Martin periodane; In dichloromethane; for 1h; Inert atmosphere;

DOI:10.1271/bbb.100053

Reference yield:

ethyl (E,E,E)-2,4,6-nonatrienoate (922528-07-2) → (E,E,E)-2,4,6-nonatrienal (57018-53-8)

Guidance literature:

ethyl (E,E,E)-2,4,6-nonatrienoate; With diisobutylaluminium hydride; In dichloromethane; at 0 ℃; for 0.75h; Inert atmosphere;

With manganese(IV) oxide; In dichloromethane; at 20 ℃;

DOI:10.1055/s-0037-1611537

Reference yield:

trans-2-pentenal (1576-87-0) + (3-methoxycarbonyl-2-propenyl)triphenylphosphonium bromide (72967-11-4) → (E,Z,E)-2,4,6-nonatrienal + (E,E,E)-2,4,6-nonatrienal (57018-53-8)

Guidance literature:

trans-2-pentenal; (3-methoxycarbonyl-2-propenyl)triphenylphosphonium bromide; With Tris(3,6-dioxaheptyl)amine; sodium hydrogencarbonate; In dichloromethane; at 20 ℃; for 12h;

With lithium aluminium tetrahydride; at 20 ℃; for 1h;

With Dess-Martin periodane; at 20 ℃; for 12h;

DOI:10.1021/jf051601i

upstream raw materials:

(2E,4E)-hepta-2,4-dienal

trans-2-pentenal

1-methoxy-buten-3-yne

cis-2-penten-1-one

Downstream raw materials:

3'-(1E/Z,3E,5E,7E,9E,11E-Tetradecahexaenyloxy)-1,2-propanediol

3'-(1E/Z,3E,5E,7E-Decatetraenyloxy)-1,2-propanediol

Refernces

• 1、 Kumazawa, Kenji,Sakai, Nao,Amma, Hiroko,Sakamoto, Satoshi,Kodama, Masaki,Wada, Yoshiyuki,Nishimura, Osamu. "Identification and formation of volatile components responsible for the characteristic aroma of mat rush (Igusa)". . p. 1231 - 1236. Retrieved 2010.
• 2、 Xia, Xuanshu,Lao, Zhiqi,Toy, Patrick H.. "Triphenylphosphine Oxide-Catalyzed Selective α,β-Reduction of Conjugated Polyunsaturated Ketones". . p. 1100 - 1104. Retrieved 2019/05/24.