(1,2-METHANOFULLERENE C60)-61-CARBOXYLIC ACID TERT-BUTYL ESTER

Base Information

Chemical Name:(1,2-METHANOFULLERENE C60)-61-CARBOXYLIC ACID TERT-BUTYL ESTER
CAS No.:150493-29-1
Molecular Formula:C66H10 O2
Molecular Weight:834.804
Hs Code.:
European Community (EC) Number:633-984-0
Nikkaji Number:J1.404.049H
Mol file:150493-29-1.mol

Synonyms:(1,2-METHANOFULLERENE C60)-61-CARBOXYLIC ACID TERT-BUTYL ESTER;TERT-BUTYL (1,2-METHANOFULLERENE C60)-61-CARBOXYLATE

Suppliers and Price of (1,2-METHANOFULLERENE C60)-61-CARBOXYLIC ACID TERT-BUTYL ESTER

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
(1,2-METHANOFULLERENE-C60)-61-CARBOXYLIC ACID TERT-BUTYL ESTER 95.00%
5MG
$ 497.33

Total 2 raw suppliers

Chemical Property of (1,2-METHANOFULLERENE C60)-61-CARBOXYLIC ACID TERT-BUTYL ESTER

Chemical Property:

PSA：26.30000
LogP:17.26550
Storage Temp.:2-8°C
XLogP3:15.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:834.068079558
Heavy Atom Count:68
Complexity:3730

Purity/Quality:

95% ^*data from raw suppliers

(1,2-METHANOFULLERENE-C60)-61-CARBOXYLIC ACID TERT-BUTYL ESTER 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26

MSDS Files:

Useful:

Canonical SMILES:CC(C)(C)OC(=O)C1C23C14C5=C6C7=C8C9=C1C%10=C%11C%12=C%13C%14=C%10C%10=C1C1=C%15C%16=C%17C%18=C%19C%20=C%21C%22=C%23C%24=C%25C%26=C(C7=C9C%11=C%26C%12=C%24C%22=C%13C%20=C%14C%18=C%10%16)C7=C%25C9=C(C4=C76)C4=C2C(=C%17C3=C%15C5=C81)C%19=C%21C4=C%239

Technology Process of (1,2-METHANOFULLERENE C60)-61-CARBOXYLIC ACID TERT-BUTYL ESTER

There total 9 articles about (1,2-METHANOFULLERENE C60)-61-CARBOXYLIC ACID TERT-BUTYL ESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: di-tert-butyl methano[60]fullerene-61,61-dicarboxylate

: 150493-29-1
tert-butyl 3′H-cyclopropa[1,9](C₆₀-I_h)[5,6]fullerene-3′-carboxylate

Guidance literature:: In 1,2-dichloro-benzene; for 6h; Inert atmosphere; Reflux;
DOI:10.1021/ol4035275

Reference yield: 56.0%

: 195453-96-4
tert-butyl 2-(dimethyl-λ⁴-sulfanylidene)acetate

: 99685-96-8,161105-99-3,161106-00-9,111138-12-6,133318-63-5,134053-11-5,134931-35-4,134931-36-5,139703-76-7,145633-27-8,175414-73-0,175414-74-1,175414-75-2,175519-12-7,175519-13-8,175519-14-9,175519-15-0,136376-46-0,144906-37-6,144906-38-7,151767-00-9,152882-97-8,152882-98-9,152882-99-0,153062-34-1,154171-74-1,154171-75-2,154333-99-0,154334-00-6,154397-63-4,154460-59-0,199456-56-9,108739-25-9,120329-57-9,120329-58-0
fullerene-C₆₀

: 150493-29-1
tert-butyl 3′H-cyclopropa[1,9](C₆₀-I_h)[5,6]fullerene-3′-carboxylate

Guidance literature:: In toluene; Ambient temperature;
DOI:10.1016/0040-4039(95)01443-L

Reference yield: 55.0%

: 5292-43-3
bromoacetic acid tert-butyl ester

: 99685-96-8,161105-99-3,161106-00-9,111138-12-6,133318-63-5,134053-11-5,134931-35-4,134931-36-5,139703-76-7,145633-27-8,175414-73-0,175414-74-1,175414-75-2,175519-12-7,175519-13-8,175519-14-9,175519-15-0,136376-46-0,144906-37-6,144906-38-7,151767-00-9,152882-97-8,152882-98-9,152882-99-0,153062-34-1,154171-74-1,154171-75-2,154333-99-0,154334-00-6,154397-63-4,154460-59-0,199456-56-9,108739-25-9,120329-57-9,120329-58-0
fullerene-C₆₀

: 150493-29-1
tert-butyl 3′H-cyclopropa[1,9](C₆₀-I_h)[5,6]fullerene-3′-carboxylate

Guidance literature:: With N,N,N',N'',N'''-pentamethyldiethylenetriamine; copper(I) bromide; In toluene; at 110 ℃; for 4h;
DOI:10.1002/ejoc.201200759