Carbamic acid, (4-nitrobutyl)-, 1,1-dimethylethyl ester (9CI)

Base Information

Chemical Name:Carbamic acid, (4-nitrobutyl)-, 1,1-dimethylethyl ester (9CI)
CAS No.:150906-46-0
Molecular Formula:C₉H₁₈N₂O₄
Molecular Weight:218.253
Hs Code.:
Mol file:150906-46-0.mol

Synonyms:Carbamic acid, (4-nitrobutyl)-, 1,1-dimethylethyl ester (9CI)

Suppliers and Price of Carbamic acid, (4-nitrobutyl)-, 1,1-dimethylethyl ester (9CI)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Carbamic acid, (4-nitrobutyl)-, 1,1-dimethylethyl ester (9CI)

Chemical Property:

PSA：0.00000
LogP:0.00000

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Carbamic acid, (4-nitrobutyl)-, 1,1-dimethylethyl ester (9CI)

There total 2 articles about Carbamic acid, (4-nitrobutyl)-, 1,1-dimethylethyl ester (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 262278-40-0
N-tert-butoxycarbonyl-4-amino-1-iodobutane

: 150906-46-0
4-(N-t-butoxycarbonylamino)-1-nitrobutane

Guidance literature:: With sodium nitrite; In N,N-dimethyl-formamide; at 20 ℃;
DOI:10.1021/acs.orglett.0c03061

Reference yield:

: 24424-99-5
di-tert-butyl dicarbonate

: 150906-46-0
4-(N-t-butoxycarbonylamino)-1-nitrobutane

Guidance literature:: Multi-step reaction with 2 steps

1.1: triethylamine / dichloromethane / 0 - 20 °C

1.2: 0 - 20 °C

2.1: sodium nitrite / N,N-dimethyl-formamide / 20 °C

With triethylamine; sodium nitrite; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/acs.orglett.0c03061

Reference yield: 63.0%

: (3-bromo-5-phenylpent-1-yn-1-yl)trimethylsilane

: 150906-46-0
4-(N-t-butoxycarbonylamino)-1-nitrobutane

: C₂₃H₃₆N₂O₄Si

Guidance literature:: 4-(N-t-butoxycarbonylamino)-1-nitrobutane; With N,N-diisopropyl-1,2-ethanediamine; potassium tert-butylate; copper(I) bromide; In 1,4-dioxane; at 20 ℃; for 0.5h; Schlenk technique; Inert atmosphere;

(3-bromo-5-phenylpent-1-yn-1-yl)trimethylsilane; In 1,4-dioxane; at 20 ℃; for 20h; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.orglett.0c03061