3,4-DI-O-ACETYL-6-O-(TERT-BUTYLDIPHENYLSILYL)-D-GLUCAL

Base Information

Chemical Name:3,4-DI-O-ACETYL-6-O-(TERT-BUTYLDIPHENYLSILYL)-D-GLUCAL
CAS No.:151797-32-9
Molecular Formula:C26H32 O6 Si
Molecular Weight:468.622
Hs Code.:
Mol file:151797-32-9.mol

Synonyms:D-arabino-Hex-1-enitol,1,5-anhydro-2-deoxy-6-O-[(1,1-dimethylethyl)diphenylsilyl]-, diacetate (9CI)

Suppliers and Price of 3,4-DI-O-ACETYL-6-O-(TERT-BUTYLDIPHENYLSILYL)-D-GLUCAL

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
3,4-Di-O-acetyl-6-O-(tert-butyldiphenylsilyl)-D-glucal Aldrich
1g
$ 129.00

Crysdot
(2R,3S,4R)-2-(((tert-Butyldiphenylsilyl)oxy)methyl)-3,4-dihydro-2H-pyran-3,4-diyldiacetate 97%
5g
$ 558.00

Chemenu
(2R,3S,4R)-2-(((tert-Butyldiphenylsilyl)oxy)methyl)-3,4-dihydro-2H-pyran-3,4-diyldiacetate 97%
5g
$ 527.00

American Custom Chemicals Corporation
3,4-DI-O-ACETYL-6-O-(TERT-BUTYLDIPHENYLSILYL)-D-GLUCAL 95.00%
5MG
$ 501.79

Alichem
3,4-Di-o-acetyl-6-o-tert-butyldiphenylsilyl-d-glucal
5g
$ 977.13

Total 2 raw suppliers

Chemical Property of 3,4-DI-O-ACETYL-6-O-(TERT-BUTYLDIPHENYLSILYL)-D-GLUCAL

Chemical Property:

Refractive Index:n20/D 1.456(lit.)
Boiling Point:509.6±50.0 °C(Predicted)
Flash Point:>230 °F
PSA：119.36000
Density:1.14±0.1 g/cm3(Predicted)
LogP:1.34710

Purity/Quality:

99% ^*data from raw suppliers

3,4-Di-O-acetyl-6-O-(tert-butyldiphenylsilyl)-D-glucal Aldrich ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 3,4-DI-O-ACETYL-6-O-(TERT-BUTYLDIPHENYLSILYL)-D-GLUCAL

There total 7 articles about 3,4-DI-O-ACETYL-6-O-(TERT-BUTYLDIPHENYLSILYL)-D-GLUCAL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 87316-22-1
(2R,3S,4R)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-3,4-dihydro-2H-pyran-3,4-diol

: 108-24-7
acetic anhydride

: 151797-32-9,312692-93-6
3,4-di-O-acetyl-6-O-(tert-butyl diphenylsilyl)-D-glucal

Guidance literature:: With pyridine; In dichloromethane;
DOI:10.1080/00397919308018600

Reference yield: 88.0%

: 180072-36-0
2,3,4-tri-O-acetyl-6-O-[(1,1-dimethylethyl)diphenylsilyl]-α-D-glucopyranosyl bromide

: 151797-32-9,312692-93-6
3,4-di-O-acetyl-6-O-(tert-butyl diphenylsilyl)-D-glucal

Guidance literature:: With bis(cyclopentadienyl)-titanium(III) chloride; In tetrahydrofuran; Ambient temperature;
DOI:10.1016/0040-4039(96)00865-9

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 151797-32-9,312692-93-6
3,4-di-O-acetyl-6-O-(tert-butyl diphenylsilyl)-D-glucal

Guidance literature:: Multi-step reaction with 3 steps

1: 98 percent / imidazole / CH₂Cl₂

2: 39 percent / TMS-Br / CH₂Cl₂ / -40 - 20 °C / other solvent

3: 88 percent / 2TiCl>2 / Ambient temperature

With 1H-imidazole; bis(cyclopentadienyl)-titanium(III) chloride; trimethylsilyl bromide; In dichloromethane;
DOI:10.1021/jo982447k