Technology Process of Tricyclo[5.3.0.02,8]deca-3,5-diene
There total 7 articles about Tricyclo[5.3.0.02,8]deca-3,5-diene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
potassium tert-butylate;
In
tetrahydrofuran;
at -10 ℃;
for 0.166667h;
Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1021/ja00224a036
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 1.) N-chlorosuccinimide, 2.) m-chloroperbenzoic acid / 1.) carbon tetrachloride, 90 deg C, 10 min, 2.) carbon tetrachloride, room temp, 18.5 h
2: 88 percent / pyridinium bromide perbromide / CCl4; acetic acid / 0.5 h / Ambient temperature
3: potassium tert-butoxide / tetrahydrofuran / 1 h
With
N-chloro-succinimide; potassium tert-butylate; pyridinium hydrobromide perbromide; 3-chloro-benzenecarboperoxoic acid;
In
tetrahydrofuran; tetrachloromethane; acetic acid;
DOI:10.1021/ja00224a036
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 99 percent / sodium sulfide monohydrate / hexamethylphosphoric acid triamide / 2.75 h / 110 °C
2: 1.) N-chlorosuccinimide, 2.) m-chloroperbenzoic acid / 1.) carbon tetrachloride, 90 deg C, 10 min, 2.) carbon tetrachloride, room temp, 18.5 h
3: 88 percent / pyridinium bromide perbromide / CCl4; acetic acid / 0.5 h / Ambient temperature
4: potassium tert-butoxide / tetrahydrofuran / 1 h
With
sodium sulfide; N-chloro-succinimide; potassium tert-butylate; pyridinium hydrobromide perbromide; 3-chloro-benzenecarboperoxoic acid;
In
tetrahydrofuran; tetrachloromethane; N,N,N,N,N,N-hexamethylphosphoric triamide; acetic acid;
DOI:10.1021/ja00224a036
