(1,2-METHANOFULLERENE C70)-71,71-DICARBOXYLIC ACID DIETHYL ESTER

Base Information

• Chemical Name: (1,2-METHANOFULLERENE C70)-71,71-DICARBOXYLIC ACID DIETHYL ESTER
• CAS No.: 153218-95-2
• Molecular Formula: C77H10O4
• Molecular Weight: 998.924
• Mol file: 153218-95-2.mol

Synonyms:DIETHYL (1,2-METHANOFULLERENE C70)-71,71-DICARBOXYLATE;(1,2-METHANOFULLERENE C70)-71,71-DICARBOXYLIC ACID DIETHYL ESTER;diethyl (1,2-methanofullerene C(70))-71

Chemical Property of (1,2-METHANOFULLERENE C70)-71,71-DICARBOXYLIC ACID DIETHYL ESTER

Chemical Property:

• PSA: 52.60000
• LogP: 19.37520
• Storage Temp.: 2-8°C

Purity/Quality:

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (1,2-METHANOFULLERENE C70)-71,71-DICARBOXYLIC ACID DIETHYL ESTER

There total 3 articles about (1,2-METHANOFULLERENE C70)-71,71-DICARBOXYLIC ACID DIETHYL ESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(+/-)-tetraethyl 1,2:56,57-bis(methano)<70>fullerene-71,71,72,72-tetracarboxylate (170503-87-4) → [5,6]fullerene-C70 (741268-81-5,741268-84-8,133227-82-4,133320-10-2,133320-11-3,133869-47-3,134054-62-9,134932-61-9,149820-05-3,149820-06-4,157903-26-9,175779-21-2,115383-22-7,958017-68-0,958017-71-5,958017-74-8,958017-77-1,958017-80-6,140630-87-1,140694-21-9,151716-50-6,157008-89-4,220062-79-3,220062-83-9) + (+/-)-tetraethyl 1,2:67,68-bis(methano)<70>fullerene-71,71,72,72-tetracarboxylate (170503-86-3) + tetraethyl 1,2:41,58-bis(methano)<70>fullerene-71,71,72,72-tetracarboxylate (170503-88-5) + C77H10O4 (153218-95-2)

Guidance literature:

With tert-butylammonium hexafluorophosphate(V); In dichloromethane; at 19.84 ℃; Further Variations:; reduction potential; Product distribution; Electrochemical reaction;

DOI:10.1002/1521-3765(20000616)6:12<2184::AID-CHEM2184>3.0.CO;2-6

Reference yield:

(+/-)-tetraethyl 1,2:67,68-bis(methano)<70>fullerene-71,71,72,72-tetracarboxylate (170503-86-3) → [5,6]fullerene-C70 (741268-81-5,741268-84-8,133227-82-4,133320-10-2,133320-11-3,133869-47-3,134054-62-9,134932-61-9,149820-05-3,149820-06-4,157903-26-9,175779-21-2,115383-22-7,958017-68-0,958017-71-5,958017-74-8,958017-77-1,958017-80-6,140630-87-1,140694-21-9,151716-50-6,157008-89-4,220062-79-3,220062-83-9) + (+/-)-tetraethyl 1,2:56,57-bis(methano)<70>fullerene-71,71,72,72-tetracarboxylate (170503-87-4) + tetraethyl 1,2:41,58-bis(methano)<70>fullerene-71,71,72,72-tetracarboxylate (170503-88-5) + C77H10O4 (153218-95-2)

Guidance literature:

With tert-butylammonium hexafluorophosphate(V); In dichloromethane; at 19.84 ℃; Further Variations:; reduction potential; Product distribution; Electrochemical reaction;

DOI:10.1002/1521-3765(20000616)6:12<2184::AID-CHEM2184>3.0.CO;2-6

Reference yield:

tetraethyl 1,2:41,58-bis(methano)<70>fullerene-71,71,72,72-tetracarboxylate (170503-88-5) → [5,6]fullerene-C70 (741268-81-5,741268-84-8,133227-82-4,133320-10-2,133320-11-3,133869-47-3,134054-62-9,134932-61-9,149820-05-3,149820-06-4,157903-26-9,175779-21-2,115383-22-7,958017-68-0,958017-71-5,958017-74-8,958017-77-1,958017-80-6,140630-87-1,140694-21-9,151716-50-6,157008-89-4,220062-79-3,220062-83-9) + (+/-)-tetraethyl 1,2:56,57-bis(methano)<70>fullerene-71,71,72,72-tetracarboxylate (170503-87-4) + (+/-)-tetraethyl 1,2:67,68-bis(methano)<70>fullerene-71,71,72,72-tetracarboxylate (170503-86-3) + C77H10O4 (153218-95-2)

Guidance literature:

With tert-butylammonium hexafluorophosphate(V); In dichloromethane; at 19.84 ℃; Further Variations:; reduction potential; Product distribution; Electrochemical reaction;

DOI:10.1002/1521-3765(20000616)6:12<2184::AID-CHEM2184>3.0.CO;2-6

upstream raw materials:

(+/-)-tetraethyl 1,2:56,57-bis(methano)<70>fullerene-71,71,72,72-tetracarboxylate

(+/-)-tetraethyl 1,2:67,68-bis(methano)<70>fullerene-71,71,72,72-tetracarboxylate

tetraethyl 1,2:41,58-bis(methano)<70>fullerene-71,71,72,72-tetracarboxylate

Downstream raw materials:

[5,6]fullerene-C₇₀

(+/-)-tetraethyl 1,2:56,57-bis(methano)<70>fullerene-71,71,72,72-tetracarboxylate

(+/-)-tetraethyl 1,2:67,68-bis(methano)<70>fullerene-71,71,72,72-tetracarboxylate

tetraethyl 1,2:41,58-bis(methano)<70>fullerene-71,71,72,72-tetracarboxylate