Technology Process of Benzyltrichlorogermane
There total 6 articles about Benzyltrichlorogermane which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
zinc(II) chloride;
In
hydrogenchloride;
in the presence of ZnCl2 impurities, refluxing (3.5-4 h); cooling to room temperature, lower layer sepn. and combining with hexaneextract of upper layer, extracts sepn. by distillation;
- Guidance literature:
-
With
zinc(II) chloride;
In
hydrogenchloride;
in the presence of ZnCl2 impurities, refluxing (6.5-7 h); cooling to room temperature, lower layer sepn. and combining with hexaneextract of upper layer, extracts sepn. by distillation;
- Guidance literature:
-
With
tetraethylammonium bromide;
In
acetonitrile;
byproducts: germanium hypoiodide; Electrolysis; cathodic electrolysis of GeCl4 (0.3 - 0.5 M) in presence of 15 vol% C6H5CH2I in 0.4 Et4NBr in abs. CH3CN, Pt electrode;; detn. by spectra and physical indices;;
DOI:10.1007/BF00959406
