Spiro[2.4]heptane-1-carboxylic acid, 1-amino-, methyl ester (9CI)

Base Information

Chemical Name:Spiro[2.4]heptane-1-carboxylic acid, 1-amino-, methyl ester (9CI)
CAS No.:669058-67-7
Molecular Formula:C₉H₁₅NO₂
Molecular Weight:169.224
Hs Code.:
Mol file:669058-67-7.mol

Synonyms:Spiro[2.4]heptane-1-carboxylic acid, 1-amino-, methyl ester (9CI)

Suppliers and Price of Spiro[2.4]heptane-1-carboxylic acid, 1-amino-, methyl ester (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Spiro[2.4]heptane-1-carboxylic acid, 1-amino-, methyl ester (9CI)

Chemical Property:

PSA：0.00000
LogP:0.00000

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

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Technology Process of Spiro[2.4]heptane-1-carboxylic acid, 1-amino-, methyl ester (9CI)

There total 2 articles about Spiro[2.4]heptane-1-carboxylic acid, 1-amino-, methyl ester (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 669058-49-5
1-nitro-spiro[2.4]heptane-1-carboxylic acid methyl ester

: 669058-67-7
methyl 1-aminospiro[2.4]heptane-1-carboxylate

Guidance literature:: With hydrogenchloride; zinc; In isopropyl alcohol; at 20 ℃; for 2h;
DOI:10.1021/jo035596y

Reference yield:

: 1528-30-9
methylenecyclopentane

: 669058-67-7
methyl 1-aminospiro[2.4]heptane-1-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 83 percent / [Rh(octanoate)2]2 / CH₂Cl₂ / 20 °C

2: 54 percent / aq. HCl; Zn dust / propan-2-ol / 2 h / 20 °C

With hydrogenchloride; zinc; [Rh(octanoate)2]2; In dichloromethane; isopropyl alcohol;
DOI:10.1021/jo035596y