Cyclohexene, 4,5-dimethoxy-4,5-dimethyl-, (4R,5S)-rel- (9CI)

Base Information

Chemical Name:Cyclohexene, 4,5-dimethoxy-4,5-dimethyl-, (4R,5S)-rel- (9CI)
CAS No.:600726-49-6
Molecular Formula:C10H18O2
Molecular Weight:170.25
Hs Code.:
Mol file:600726-49-6.mol

Synonyms:Cyclohexene, 4,5-dimethoxy-4,5-dimethyl-, (4R,5S)-rel- (9CI)

Suppliers and Price of Cyclohexene, 4,5-dimethoxy-4,5-dimethyl-, (4R,5S)-rel- (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Cyclohexene, 4,5-dimethoxy-4,5-dimethyl-, (4R,5S)-rel- (9CI)

Chemical Property:

PSA：18.46000
LogP:2.14660

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

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Technology Process of Cyclohexene, 4,5-dimethoxy-4,5-dimethyl-, (4R,5S)-rel- (9CI)

There total 4 articles about Cyclohexene, 4,5-dimethoxy-4,5-dimethyl-, (4R,5S)-rel- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 600726-47-4
(4R,5S)-4,5-dimethoxyocta-4,5-dimethyl-1,7-diene

: 600726-49-6,746622-75-3
(1R,2S)-1,2-dimethyl-1,2-dimethoxycyclohex-4-ene

Guidance literature:: With Grubbs catalyst first generation;
DOI:10.1016/S0040-4039(03)01224-3

Reference yield:

: 176798-33-7
2,2,3,3-tetramethoxybutane

: 600726-49-6,746622-75-3
(1R,2S)-1,2-dimethyl-1,2-dimethoxycyclohex-4-ene

Guidance literature:: Multi-step reaction with 2 steps

1: 43 percent / TiCl₄ / nitromethane; CH₂Cl₂ / 2 h / -90 °C

2: 90 percent / Cl₂(PCy₃)2Ru=CHPh / CH₂Cl₂ / 1.15 h / 20 °C

With titanium tetrachloride; Grubbs catalyst first generation; In nitromethane; dichloromethane;
DOI:10.1002/ejoc.200400042

Reference yield:

: 181586-74-3
(2R,3R,5R,6R)-5,6-dimethoxy-5,6-dimethyl[1,4]dioxane-2,3-dicarboxylic acid dimethyl ester

: 600726-49-6,746622-75-3
(1R,2S)-1,2-dimethyl-1,2-dimethoxycyclohex-4-ene

Guidance literature:: Multi-step reaction with 2 steps

1: 60 percent / TiCl₄ / nitromethane; CH₂Cl₂ / 2 h / -90 °C

2: 90 percent / Cl₂(PCy₃)2Ru=CHPh / CH₂Cl₂ / 1.15 h / 20 °C

With titanium tetrachloride; Grubbs catalyst first generation; In nitromethane; dichloromethane;
DOI:10.1002/ejoc.200400042