Bromotriethylsilane

Base Information

• Chemical Name: Bromotriethylsilane
• CAS No.: 1112-48-7
• Molecular Formula: C6H15BrSi
• Molecular Weight: 195.175
• Hs Code.: 2931900090
• European Community (EC) Number: 214-191-5
• DSSTox Substance ID: DTXSID7061489
• Nikkaji Number: J217.231C
• Wikidata: Q72513180
• Mol file: 1112-48-7.mol

Synonyms:Bromotriethylsilane;Triethylbromosilane;1112-48-7;bromo(triethyl)silane;Silane, bromotriethyl-;EINECS 214-191-5;C6H15BrSi;C6-H15-Br-Si;SCHEMBL706177;DTXSID7061489;MFCD00000049;AKOS025213763;Bromotriethylsilane, >=95.0% (GC);BS-44071;B5890;CS-0198858;D89174;J-002545

Chemical Property of Bromotriethylsilane

Chemical Property:

• Vapor Pressure: 3.32mmHg at 25°C
• Melting Point: -50°C
• Refractive Index: 1.437
• Boiling Point: 159 °C at 760 mmHg
• Flash Point: 56.2 °C
• PSA: 0.00000
• Density: 1.135 g/cm³
• LogP: 3.38650
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 194.01264
• Heavy Atom Count: 8
• Complexity: 51.3

Purity/Quality:

99% ^*data from raw suppliers

Bromotriethylsilane >96.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 10-34
• Safety Statements: 26-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC[Si](CC)(CC)Br

Technology Process of Bromotriethylsilane

There total 47 articles about Bromotriethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

triethylsilyl phenylselenide (76358-43-5) → triethyl-bromo-silane (1112-48-7) + diphenyl diselenide (1666-13-3)

Guidance literature:

With bromine; at 0 ℃;

DOI:10.1021/jo00320a012

Reference yield: 93.0%

triethylsilane (617-86-7) → triethyl-bromo-silane (1112-48-7)

Guidance literature:

With Br₂; In further solvent(s); (C2H5)3SiH and Br2 in C2H5Br;;

DOI:10.1021/jo01149a018

Reference yield: 87.0%

hexaethyldisilane (1633-09-6) → triethyl-bromo-silane (1112-48-7)

Guidance literature:

With Br₂; In diethyl ether; at room temp.;;

DOI:10.1021/jo50018a019

upstream raw materials:

triethylsilane

Methyl 3-bromopropionate

triethylsilylamine

2-bromopropyl-triethylsilane

Downstream raw materials:

bis(triethylsilyl)acetylene

2-triethylsilylacetylene

triethylsilyl fluoride

hexaethyldisilane

Refernces

• 1、 Kraus, C. A.,Nilson, W. K.. "-". . p. 195 - 202. Retrieved 1934.
• 2、 Bailey,Sommer,Whitmore. "-". . p. 435. Retrieved 1948.
• 3、 Chatgilialoglu, C.,Ingold, K. U.,Scaiano, J. C.,Woynar, H.. "Absolute Rate Constants for Some Reaction Involving Triethylsilyl Radicals in Solution". . p. 3231 - 3232. Retrieved 1981.
• 4、 Mackay et al.. "". . p. 49. Retrieved 1968.
• 5、 Westermark. "-". . p. 1086. Retrieved 1954.
• 6、 Almenara,Azpeitia,Garralda,Huertos. "Rh(iii)-Catalysed solvent-free hydrodehalogenation of alkyl halides by tertiary silanes". supporting information. p. 16225 - 16231. Retrieved 2018/11/30.
• 7、 Srithanakit, Phatsupha,Chavasiri, Warinthorn. "A new and efficient method for the synthesis of bromosilanes from hydrosilanes using Br3CCOOEt/PdCl2 as the catalyst". experimental part. p. 2505 - 2507. Retrieved 2011/05/09.