Einecs 266-711-5

Base Information

• Chemical Name: Einecs 266-711-5
• CAS No.: 67519-00-0
• Molecular Formula: C10H16 O2
• Molecular Weight: 168.236
• European Community (EC) Number: 266-711-5
• Nikkaji Number: J305.058K
• Mol file: 67519-00-0.mol

Synonyms:EINECS 266-711-5;(1)-exo-3,3-Dimethylbicyclo(2.2.1)heptane-2-carboxylic acid;67519-00-0

Chemical Property of Einecs 266-711-5

Chemical Property:

• XLogP3: 2.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 168.115029749
• Heavy Atom Count: 12
• Complexity: 220

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1(C2CCC(C2)C1C(=O)O)C
• Isomeric SMILES: CC1([C@H]2CC[C@H](C2)[C@@H]1C(=O)O)C

Technology Process of Einecs 266-711-5

There total 18 articles about Einecs 266-711-5 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

Camphene epoxide (875-03-6,62318-94-9,69685-54-7,69685-55-8,90365-31-4,481660-32-6) → 3,3-Dimethylbicyclo<2.2.1>heptan-2-one (50896-19-0) + 3,3-Dimethylbicyclo<2.2.1>heptan-2-carboxylic acid (474-09-9,474-10-2,52557-98-9,67518-96-1,67518-98-3,67519-00-0,85506-67-8)

Guidance literature:

With jones' reagent; In acetone; at 15 - 20 ℃; for 0.5h;

Reference yield:

→ 3,3-Dimethyl-bicyclo<1.2.2>heptan-carbonsaeure-(2exo) (474-09-9,474-10-2,52557-98-9,67518-96-1,67518-98-3,67519-00-0,85506-67-8)

Guidance literature:

3,3-Dimethyl-bicyclo<1.2.2>heptanon-(6)-carbonsaeure-(2endo)-lactol, Wolff-Kishner-Red.;

Reference yield:

1-(3,3-Dimethyl-bicyclo<2.2.1>hept-2-yl)ethanon (15780-34-4,15820-33-4,42370-07-0,134591-16-5,134591-40-5) → 2-exo-10-camphanoic acid (67519-00-0)

Guidance literature:

With potassium hydroxide; potassium hypochlorite;

DOI:10.1021/ja01141a041

upstream raw materials:

1-(3,3-Dimethyl-bicyclo<2.2.1>hept-2-yl)ethanon

4-methyl-pent-3-en-2-one

cyclopenta-1,3-diene

exo-3,3-dimethyl-2-norbornanacetaldehyde

Downstream raw materials:

(3,3-dimethylbicyclo[2.2.1]heptan-2-yl)methanol

exo-3,3-dimethyl-2-norbornanacetaldehyde

(+/-)-isocamphenilanic acid-chloride

3-((1S,2R,4R)-3,3-Dimethyl-bicyclo[2.2.1]hept-2-yl)-propionyl chloride