2,3-Dimethyl-5-(prop-2-en-1-yl)cyclopent-2-en-1-one

Base Information

Chemical Name:2,3-Dimethyl-5-(prop-2-en-1-yl)cyclopent-2-en-1-one
CAS No.:466634-65-1
Molecular Formula:C10H14O
Molecular Weight:150.21756
Hs Code.:
DSSTox Substance ID:DTXSID10479960
Nikkaji Number:J1.730.234E
Mol file:466634-65-1.mol

Synonyms:466634-65-1;2,3-Dimethyl-5-(prop-2-en-1-yl)cyclopent-2-en-1-one;DTXSID10479960

Suppliers and Price of 2,3-Dimethyl-5-(prop-2-en-1-yl)cyclopent-2-en-1-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,3-Dimethyl-5-(prop-2-en-1-yl)cyclopent-2-en-1-one

Chemical Property:

PSA：17.07000
LogP:2.48790
XLogP3:2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:150.104465066
Heavy Atom Count:11
Complexity:223

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=C(C(=O)C(C1)CC=C)C

Technology Process of 2,3-Dimethyl-5-(prop-2-en-1-yl)cyclopent-2-en-1-one

There total 4 articles about 2,3-Dimethyl-5-(prop-2-en-1-yl)cyclopent-2-en-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 1121-05-7
2,3-dimethylcyclopent-2-enone

: 106-95-6
allyl bromide

: 466634-65-1
5-allyl-2,3-dimethyl-cyclopent-2-enone

Guidance literature:: With manganese triacetate; In benzene; for 10h; Heating;
DOI:10.1016/S0040-4039(02)00726-8 DOI:10.1016/j.tet.2005.06.031

Reference yield: 68.0%

: methyl 1-allyl-3,4-dimethyl-2-oxocyclopent-3-ene-1-carboxylate

: 466634-65-1
5-allyl-2,3-dimethyl-cyclopent-2-enone

Guidance literature:: With potassium tert-butylate; In methanol; at 80 ℃; for 3h; Schlenk technique;
DOI:10.1021/acs.orglett.1c01569

Reference yield:

: 13201-46-2
2-methylbut-2-enoic acid

: 466634-65-1
5-allyl-2,3-dimethyl-cyclopent-2-enone

Guidance literature:: Multi-step reaction with 3 steps

1: dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver hexafluoroantimonate; sodium carbonate / 1,2-dichloro-ethane / 3 h / 130 °C / Schlenk technique

2: sodium carbonate / methanol / 3 h / 40 °C / Schlenk technique

3: potassium tert-butylate / methanol / 3 h / 80 °C / Schlenk technique

With silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; potassium tert-butylate; sodium carbonate; In methanol; 1,2-dichloro-ethane;
DOI:10.1021/acs.orglett.1c01569