DI-(2-Pyridyl)(diphenylphosphino)amine

Base Information

• Chemical Name: DI-(2-Pyridyl)(diphenylphosphino)amine
• CAS No.: 472959-76-5
• Molecular Formula: C22H18N3P
• Molecular Weight: 355.379
• DSSTox Substance ID: DTXSID40433474
• Nikkaji Number: J1.733.911G
• Wikidata: Q82247631
• Mol file: 472959-76-5.mol

Synonyms:472959-76-5;DI-(2-PYRIDYL)(DIPHENYLPHOSPHINO)AMINE;N-diphenylphosphanyl-N-pyridin-2-ylpyridin-2-amine;1,1-DIPHENYL-N,N-BIS(PYRIDIN-2-YL)PHOSPHANAMINE;N-(Diphenylphosphino)-N-(pyridin-2-yl)pyridin-2-amine;AGN-PC-0MWHO1;SCHEMBL230462;DTXSID40433474;[bis(2-pyridyl)amino]diphenylphosphine;Bis(2-pyridyl)(diphenylphosphino)amine;EN300-20639337;N-(diphenylphosphanyl)-N-(pyridin-2-yl)pyridin-2-amine

Chemical Property of DI-(2-Pyridyl)(diphenylphosphino)amine

Chemical Property:

• XLogP3: 5.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 355.12383458
• Heavy Atom Count: 26
• Complexity: 370

Purity/Quality:

97% ^*data from raw suppliers

DI-(2-PYRIDYL)(DIPHENYLPHOSPHINO)AMINE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)N(C3=CC=CC=N3)C4=CC=CC=N4

Technology Process of DI-(2-Pyridyl)(diphenylphosphino)amine

There total 1 articles about DI-(2-Pyridyl)(diphenylphosphino)amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

di(pyridin-2-yl)amine (1202-34-2) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → (bis(2-pyridyl)amino)diphenylphosphane (472959-76-5)

Guidance literature:

With n-butyllithium; In diethyl ether; hexane; at 20 ℃; for 48h;

DOI:10.1002/1521-3773(20020503)41:9<1521::AID-ANIE1521>3.0.CO;2-R

Reference yield: 98.0%

chloro(1,5-cyclooctadiene)rhodium(I) dimer + (bis(2-pyridyl)amino)diphenylphosphane (472959-76-5) → Rh2Cl2((bis(2-pyridyl)amino)diphenylphosphane)2(1,5-cyclooctadiene) (943248-69-9)

Guidance literature:

In tetrahydrofuran; at room temp.; washed (hexane); NMR;

DOI:10.1002/anie.200604988

Reference yield: 75.0%

dichloro(1,5-cyclooctadiene)palladium(II) (12107-56-1) + (bis(2-pyridyl)amino)diphenylphosphane (472959-76-5) → (C5H4N)2NP(C6H5)2PdCl2 (473256-55-2)

Guidance literature:

In dichloromethane; (Ar), mixed; layered with diethyl ether for 1 week, elem. anal., XRD;

DOI:10.1002/1521-3773(20020503)41:9<1521::AID-ANIE1521>3.0.CO;2-R

upstream raw materials:

di(pyridin-2-yl)amine

chloro-diphenylphosphine

Downstream raw materials:

Rh₂Cl₂((bis(2-pyridyl)amino)diphenylphosphane)2(1,5-cyclooctadiene)

(C₅H₄N)2NP(C₆H₅)2PdCl₂