Carbamic acid, [1-(2-oxoethyl)cyclopropyl]-, 1,1-dimethylethyl ester (9CI)

Base Information

Chemical Name:Carbamic acid, [1-(2-oxoethyl)cyclopropyl]-, 1,1-dimethylethyl ester (9CI)
CAS No.:497861-78-6
Molecular Formula:C10H17NO3
Molecular Weight:199.24688
Hs Code.:
Mol file:497861-78-6.mol

Synonyms:Carbamic acid, [1-(2-oxoethyl)cyclopropyl]-, 1,1-dimethylethyl ester (9CI)

Suppliers and Price of Carbamic acid, [1-(2-oxoethyl)cyclopropyl]-, 1,1-dimethylethyl ester (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
tert-Butyl(1-(2-oxoethyl)cyclopropyl)carbamate 97%
1g
$ 804.00

Total 4 raw suppliers

Chemical Property of Carbamic acid, [1-(2-oxoethyl)cyclopropyl]-, 1,1-dimethylethyl ester (9CI)

Chemical Property:

PSA：0.00000
LogP:0.00000

Purity/Quality:

97% ^*data from raw suppliers

tert-Butyl(1-(2-oxoethyl)cyclopropyl)carbamate 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Carbamic acid, [1-(2-oxoethyl)cyclopropyl]-, 1,1-dimethylethyl ester (9CI)

There total 5 articles about Carbamic acid, [1-(2-oxoethyl)cyclopropyl]-, 1,1-dimethylethyl ester (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 753023-57-3
tert-butyl N-[1-(2-hydroxyethyl)cyclopropyl]carbamate

: 497861-78-6
tert-butyl N-[1-(2-oxoethyl)cyclopropyl]carbamate

Guidance literature:: With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; trichloroisocyanuric acid; In dichloromethane; at 0 ℃; for 1h;

Reference yield:

: tert-butyl N-{1-[2-(benzyloxy)ethyl]cyclopropyl}carbamate

: 497861-78-6
tert-butyl N-[1-(2-oxoethyl)cyclopropyl]carbamate

Guidance literature:: Multi-step reaction with 2 steps

1: 5%-palladium/activated carbon; hydrogen / methanol / 72 h / 20 °C / 15751.6 Torr / Inert atmosphere

2: Dess-Martin periodane; sodium hydrogencarbonate / dichloromethane / 0.5 h / 20 °C / Molecular sieve

With 5%-palladium/activated carbon; hydrogen; sodium hydrogencarbonate; Dess-Martin periodane; In methanol; dichloromethane; 2: |Dess-Martin Oxidation;
DOI:10.1002/ejoc.201403387

Reference yield:

: 388095-22-5
1-[2-(benzyloxy)ethyl]cyclopropan-1-amine

: 497861-78-6
tert-butyl N-[1-(2-oxoethyl)cyclopropyl]carbamate

Guidance literature:: Multi-step reaction with 3 steps

1: sodium hydroxide / water; tert-butyl alcohol / 17 h / 0 - 20 °C

2: 5%-palladium/activated carbon; hydrogen / methanol / 72 h / 20 °C / 15751.6 Torr / Inert atmosphere

3: Dess-Martin periodane; sodium hydrogencarbonate / dichloromethane / 0.5 h / 20 °C / Molecular sieve

With 5%-palladium/activated carbon; hydrogen; sodium hydrogencarbonate; Dess-Martin periodane; sodium hydroxide; In methanol; dichloromethane; water; tert-butyl alcohol; 3: |Dess-Martin Oxidation;
DOI:10.1002/ejoc.201403387