7-ACETOXY-1-HEPTENE

Base Information

• Chemical Name: 7-ACETOXY-1-HEPTENE
• CAS No.: 5048-30-6
• Molecular Formula: C9H16O2
• Molecular Weight: 156.22
• Hs Code.: 2915390090
• Mol file: 5048-30-6.mol

Synonyms:7-ACETOXY-1-HEPTENE;ACETIC ACID 6-HEPTEN-1-YL ESTER;6-HEPTEN-1-YL ACETATE;6-Heptenyl acetate;Acetic Acid 6-Heptenyl Ester

Chemical Property of 7-ACETOXY-1-HEPTENE

Chemical Property:

• Vapor Pressure: 0.289mmHg at 25°C
• Refractive Index: 1.428
• Boiling Point: 202.7°Cat760mmHg
• Flash Point: 75.8°C
• PSA: 26.30000
• Density: 0.889g/cm³
• LogP: 2.29590

Purity/Quality:

98%,99%, ^*data from raw suppliers

6-Heptenyl Acetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 7-ACETOXY-1-HEPTENE

There total 5 articles about 7-ACETOXY-1-HEPTENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

4-iodobutyl acetate (40596-44-9) + 2-(allylthio)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane (145732-26-9) → 1-acetoxy-6-heptene (5048-30-6)

Guidance literature:

With bis(tri-n-butyltin); In benzene-d6; at 25 ℃; for 18h; Irradiation;

DOI:10.1016/S0040-4039(00)60898-5

Reference yield: 24.0%

Bromo-acetic acid 3-vinyl-hept-6-enyl ester (212008-54-3) → 1-acetoxy-6-heptene (5048-30-6) + Acetic acid 3-vinyl-hept-6-enyl ester + 9-methyl-4-oxabicyclo[6.3.0]undecan-5-one

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; for 1h; Heating;

DOI:10.1021/ja980908d

Reference yield:

7-(tetrahydropyran-2-yloxy)hept-1-ene (100250-37-1) → 1-acetoxy-6-heptene (5048-30-6)

Guidance literature:

Multi-step reaction with 2 steps

1: aqueous phosphoric acid / 180 °C

With phosphoric acid;

upstream raw materials:

6-hepten-1-ol

acetic anhydride

4-iodobutyl acetate

2-(allylthio)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane

Downstream raw materials:

5-methyl-1-phenyl-5-hexen-3-ol

Refernces

• 1、 Curran,Yoo. "New reagents for radical allylations". . p. 6931 - 6934. Retrieved 2007/10/02.