2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE RUTHENIUM(II) CARBONYL, COMPLEX WITH TETRAHYDROFURAN

Base Information

Chemical Name:2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE RUTHENIUM(II) CARBONYL, COMPLEX WITH TETRAHYDROFURAN
CAS No.:55059-68-2
Molecular Formula:C41H52N4O2Ru++
Molecular Weight:733.96
Hs Code.:

Synonyms:2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE RUTHENIUM(II) CARBONYL, COMPLEX WITH TETRAHYDROFURAN;octaethylporphine ruthenium(II) carbonyl/ tetrahydrofuran

Suppliers and Price of 2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE RUTHENIUM(II) CARBONYL, COMPLEX WITH TETRAHYDROFURAN

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE RUTHENIUM(II) CARBONYL, COMPLEX WITH TETRAHYDROFURAN

Chemical Property:

PSA：25.11000
LogP:6.81390

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE RUTHENIUM(II) CARBONYL, COMPLEX WITH TETRAHYDROFURAN

There total 2 articles about 2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE RUTHENIUM(II) CARBONYL, COMPLEX WITH TETRAHYDROFURAN which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 106117-28-6,991-75-3
2,3,7,8,12,13,17,18-octaethylporphyrin

: hexakis(N,N-dimethylformamide)ruthenium(III) trifluoromethylsulfonate

: 55059-68-2
{Ru(II)(octaethylporphyrin(2-))(CO)(tetrahydrofuran)}

Guidance literature:: In N,N-dimethyl-formamide; mixt. of Ru compd. and ligand in DMF was purged with Ar for 15 min at room temp.; refluxed with stirring in dark for 6 h under Ar; UV monitoring; concd.; chromd. (alumina, CH2Cl2, 10% THF/MeOH); recrystd. (10% THF/toluene); elem. anal.;
DOI:10.1021/ic800616q

Reference yield:

: 113903-23-4
{Ru(II)(octaethylporphyrin^(2-))(tetrahydrofuran)2}

: 55059-68-2
{Ru(II)(octaethylporphyrin(2-))(CO)(tetrahydrofuran)}

Guidance literature:: With carbon monoxide; In tetrahydrofuran; byproducts: THF; 1 atm CO bubbled for 30 s, 20°C; monitored by UV/VIS-spectrometry (540-550 nm); Kinetics;
DOI:10.1016/S0020-1693(00)91897-8