4-Methoxy-4'-methylbiphenyl

Base Information

• Chemical Name: 4-Methoxy-4'-methylbiphenyl
• CAS No.: 53040-92-9
• Molecular Formula: C14H14O
• Molecular Weight: 198.265
• Hs Code.: 2909309090
• DSSTox Substance ID: DTXSID90364805
• Nikkaji Number: J622.170J
• Wikidata: Q82148963
• Mol file: 53040-92-9.mol

Synonyms:4-Methoxy-4'-methylbiphenyl;53040-92-9;1-methoxy-4-(4-methylphenyl)benzene;4-methoxy-4'-methyl-1,1'-biphenyl;4-Methoxy-4//'-methylbiphenyl;methyl 4'-methyl[1,1'-biphenyl]-4-yl ether;4'-Methoxy-4-methyl-biphenyl;Anisole,p-(p-tolyl)-;4-(4-Methylphenyl)anisole;4-methy-4'-methoxybiphenyl;4'-methoxy-4-methylbiphenyl;4-Methyl-4'-methoxybiphenyl;SCHEMBL295716;4-methoxy-4'-methyl-biphenyl;4-Methoxy-4/'-methylbiphenyl;DTXSID90364805;4-METHOXY-4-METHYLBIPHENYL;4-methoxyl-4'-methyl-1,1'-biphenyl;AKOS004116240;AC-18703;BB 0223397;F75332;AB-131/11435003

Chemical Property of 4-Methoxy-4'-methylbiphenyl

Chemical Property:

• Melting Point: 181-182℃
• Refractive Index: 1.552
• Boiling Point: 313.9 °C at 760 mmHg
• Flash Point: 122.9 °C
• PSA: 9.23000
• Density: 1.016 g/cm³
• LogP: 3.67060
• XLogP3: 4.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 198.104465066
• Heavy Atom Count: 15
• Complexity: 174

Purity/Quality:

98%Min ^*data from raw suppliers

4-METHOXY-4'-METHYLBIPHENYL ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)C2=CC=C(C=C2)OC

Technology Process of 4-Methoxy-4'-methylbiphenyl

There total 343 articles about 4-Methoxy-4'-methylbiphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-fluoro-4-methoxybenzene (459-60-9) + para-methylphenylmagnesium bromide (4294-57-9) → (4,4'-dimethyl-1,1'-biphenyl) (613-33-2) + 4-(4-tolyl)anisole (53040-92-9)

Guidance literature:

With C₆₈H₇₂Cl₂N₆NiP₂; In diethyl ether; at 25 ℃; for 12h; Inert atmosphere;

DOI:10.1002/chem.201001022

Reference yield: 95.0%

4-chloromethoxybenzene (623-12-1) + para-methylphenylmagnesium bromide (4294-57-9) → (4,4'-dimethyl-1,1'-biphenyl) (613-33-2) + 4-(4-tolyl)anisole (53040-92-9)

Guidance literature:

With C₆₈H₇₂Cl₂N₆NiP₂; In diethyl ether; at 25 ℃; for 12h; Inert atmosphere;

DOI:10.1002/chem.201001022

Reference yield: 90.0%

4-tolyl iodide (624-31-7) + (p-methoxyphenyl)dimethylsilanol (22868-26-4) → (4,4'-dimethyl-1,1'-biphenyl) (613-33-2) + 4-(4-tolyl)anisole (53040-92-9)

Guidance literature:

With bis(η3-allyl-μ-chloropalladium(II)); triphenyl-arsane; caesium carbonate; In toluene; at 90 ℃; for 6h;

DOI:10.1021/ol034328j

upstream raw materials:

4-(4-methyl-cyclohex-1-enyl)-anisole

4'-methyl-biphenyl-4-ol

dimethyl sulfate

4-chloromethoxybenzene

Downstream raw materials:

terephthalic acid

6-[(Z)-2-(4'-Methoxy-biphenyl-4-yl)-vinyl]-2,4-dimethyl-phenanthrene

C₂₃H₁₈N₂O₄S