2-Methoxy(dichlorophosphino)benzene

Base Information

Chemical Name:2-Methoxy(dichlorophosphino)benzene
CAS No.:58325-49-8
Molecular Formula:C7H7Cl2OP
Molecular Weight:209.009641
Hs Code.:
DSSTox Substance ID:DTXSID50400536
Nikkaji Number:J1.285.613J
Mol file:58325-49-8.mol

Synonyms:Dichloro-(2-methoxyphenyl)phosphane;2-METHOXY(DICHLOROPHOSPHINO)BENZENE;58325-49-8;2-Methoxyphenyldichlorophosphine;SCHEMBL2230609;DTXSID50400536

Suppliers and Price of 2-Methoxy(dichlorophosphino)benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
2-METHOXY(DICHLOROPHOSPHINO)BENZENE 95.00%
5MG
$ 498.18

Total 2 raw suppliers

Chemical Property of 2-Methoxy(dichlorophosphino)benzene

Chemical Property:

Boiling Point:267.9±23.0 °C(Predicted)
PSA：22.82000
LogP:3.11000
XLogP3:3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:207.9611572
Heavy Atom Count:11
Complexity:121

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

2-METHOXY(DICHLOROPHOSPHINO)BENZENE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=CC=CC=C1P(Cl)Cl

Technology Process of 2-Methoxy(dichlorophosphino)benzene

There total 2 articles about 2-Methoxy(dichlorophosphino)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.4%

: 578-57-4
2-bromoanisole

: 58325-49-8
2-anisyldichlorophosphine

Guidance literature:: 2-bromoanisole; With n-butyllithium; In diethyl ether; hexane; at 0 ℃; for 2h;

With zinc(II) chloride; In diethyl ether; hexane; at 20 ℃; for 2h;

With phosphorus trichloride; In diethyl ether; hexane; for 20h; Heating;
DOI:10.1016/S0022-328X(99)00711-1

Reference yield:

: 58325-49-8
2-anisyldichlorophosphine

Guidance literature:: 2-Methoxy-benzoldiazonium-fluoroborat in Ethylacetat (Suspens.), 1) PCl3, , (- > nicht isol. Zwischenprod.), 2) Mg, (30-50grad);
DOI:10.1021/ja01481a004

Reference yield: 71.6%

: 104-95-0
(4-bromophenyl)thioanisole

: 58325-49-8
2-anisyldichlorophosphine

: (2-methoxyphenyl)bis(4-thiomethylphenyl)phosphine

Guidance literature:: (4-bromophenyl)thioanisole; With n-butyllithium; In diethyl ether; hexane; at 0 ℃;

2-anisyldichlorophosphine; In diethyl ether; hexane; at 0 ℃;
DOI:10.1016/S0022-328X(99)00711-1