Bicyclo[2.2.1]hept-5-ene-2-methanol, 3-[(methoxymethoxy)methyl]-, (1R,2S,3R,4S)-rel- (9CI)

Base Information

Chemical Name:Bicyclo[2.2.1]hept-5-ene-2-methanol, 3-[(methoxymethoxy)methyl]-, (1R,2S,3R,4S)-rel- (9CI)
CAS No.:512791-23-0
Molecular Formula:C11H18O3
Molecular Weight:198.26
Hs Code.:
Mol file:512791-23-0.mol

Synonyms:Bicyclo[2.2.1]hept-5-ene-2-methanol, 3-[(methoxymethoxy)methyl]-, (1R,2S,3R,4S)-rel- (9CI)

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Chemical Property of Bicyclo[2.2.1]hept-5-ene-2-methanol, 3-[(methoxymethoxy)methyl]-, (1R,2S,3R,4S)-rel- (9CI)

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Technology Process of Bicyclo[2.2.1]hept-5-ene-2-methanol, 3-[(methoxymethoxy)methyl]-, (1R,2S,3R,4S)-rel- (9CI)

There total 3 articles about Bicyclo[2.2.1]hept-5-ene-2-methanol, 3-[(methoxymethoxy)methyl]-, (1R,2S,3R,4S)-rel- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 131694-93-4
(-)-methyl (1R,4S)-3-endo-<(methoxymethoxy)methyl>bicyclo<2.2.1>hept-5-ene-2-endo-carboxylate

: 131694-89-8,512791-23-0
(-)-(1R,4S)-3-endo-<(methoxymethoxy)methyl>bicyclo<2.2.1>hept-5-ene-2-endo-methanol

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran; at 0 ℃; for 0.25h;

Reference yield: 67.0%

: 941567-71-1,448922-61-0
(1R,2S,3R,4S)-bicyclo[2.2.1]hept-5-ene-2,3-dimethanol

: 107-30-2
chloromethyl methyl ether

: 512791-23-0
{3-[(methoxymethoxy)methyl]bicyclo[2.2.1]hept-5-en-2-yl}methan-1-ol

(methoxymethoxy)-{3-[(methoxymethoxy)methyl]bicyclo[2.2.1]hept-5-en-2-yl}methane: (methoxymethoxy)-{3-[(methoxymethoxy)methyl]bicyclo[2.2.1]hept-5-en-2-yl}methane

Guidance literature:: (1R,2S,3R,4S)-bicyclo[2.2.1]hept-5-ene-2,3-dimethanol; With sodium hydride; In tetrahydrofuran; for 1h;

chloromethyl methyl ether; In tetrahydrofuran; for 1h;
DOI:10.3390/70600475

Reference yield:

: 131726-11-9
(2,S)-endo-methoxycarbonyl-(3,R)-endo-hydroxymethylbicyclo<2.2.1>heptene-5

: 131694-89-8,512791-23-0
(-)-(1R,4S)-3-endo-<(methoxymethoxy)methyl>bicyclo<2.2.1>hept-5-ene-2-endo-methanol

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / diisopropylethylamine / CH₂Cl₂ / Ambient temperature

2: 89 percent / LiAlH₄ / tetrahydrofuran / 0.25 h / 0 °C

With lithium aluminium tetrahydride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; dichloromethane;