Bicyclo[2.2.1]heptan-1-amine hydrochloride

Base Information

• Chemical Name: Bicyclo[2.2.1]heptan-1-amine hydrochloride
• CAS No.: 75934-56-4
• Molecular Formula: C₇H₁₃N*ClH
• Molecular Weight: 147.648
• European Community (EC) Number: 822-405-9
• DSSTox Substance ID: DTXSID20505507
• NSC Number: 133403
• Mol file: 75934-56-4.mol

Synonyms:bicyclo[2.2.1]heptan-1-amine hydrochloride;75934-56-4;bicyclo[2.2.1]heptan-1-amine;hydrochloride;MFCD26407607;Norbornan-1-amine HCl;1-Aminobicyclo[2.2.1]heptane Hydrochloride;SCHEMBL23877623;DTXSID20505507;NSC133403;AKOS026742296;NSC-133403;AS-79454;SY153705;BICYCLO[2.2.1]HEPTAN-1-AMINE HCL;bicyclo[2.2.1]heptan-1-aminehydrochloride;CS-0092275;EN300-133885;W16245;Z1650039442;Bicyclo[2.2.1]heptan-1-amine--hydrogen chloride (1/1)

Chemical Property of Bicyclo[2.2.1]heptan-1-amine hydrochloride

Chemical Property:

• Vapor Pressure: 2.54mmHg at 25°C
• Boiling Point: 159.1°C at 760 mmHg
• Flash Point: 47.7°C
• Density: 1.033g/cm³
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 147.0814771
• Heavy Atom Count: 9
• Complexity: 101

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CC2(CCC1C2)N.Cl

Technology Process of Bicyclo[2.2.1]heptan-1-amine hydrochloride

There total 1 articles about Bicyclo[2.2.1]heptan-1-amine hydrochloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bicyclo[2.2.1]hept-1-yl-(4,4,5,5-tetramethyl-[1,3]dioxolan-2-ylidene)-amine → 1-aminonorbornane hydrochloride (75934-56-4)

Guidance literature:

With hydrogenchloride; In ethanol; for 10h; Heating;

DOI:10.1021/ol0479951

Reference yield: 24.0%

1-aminonorbornane hydrochloride (75934-56-4) + p-toluenesulfonyl chloride (98-59-9) → N-(l-norbornyl)-4-toluenesulfonamide (75934-55-3)

Guidance literature:

With sodium hydroxide; for 5h;

DOI:10.1021/jo00316a014

Reference yield:

1-aminonorbornane hydrochloride (75934-56-4) → 1-norbornyl benzoate (92787-87-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 20 percent / sodium nitrite / acetic acid

2: 54 percent / 18 h / Heating

With sodium nitrite; In acetic acid;

DOI:10.1021/jo00199a024

Downstream raw materials:

N-(l-norbornyl)-4-toluenesulfonamide

1-norbornyl benzoate

N-(1-norbornyl)-N-nitro-4-toluenesulfonamide