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Technology Process of (S)-Siphos-PE

(S)-Siphos-PE

Base Information
  • Chemical Name:(S)-Siphos-PE
  • CAS No.:500997-70-6
  • Molecular Formula:C33H32NO2P
  • Molecular Weight:505.59
  • Hs Code.:
  • European Community (EC) Number:637-119-8,637-120-3
  • Nikkaji Number:J1.876.565I,J2.297.084D
  • Wikidata:Q76416607
  • Mol file:500997-70-6.mol
(S)-Siphos-PE

Synonyms:(S)-SIPHOS-PE;500997-69-3;500997-70-6;(R)-SIPHOS-PE;(Ra,R,R)-SIPHOS-PE;Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,10,11,12,13-tetrahydro-N,N-bis[(1R)-1-phenylethyl]-, (11aR)-;N,N-Bis[(1R)-1-phenylethyl]-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine;MFCD08459342;(Sa,R,R)-SIPHOS-PE;SCHEMBL17227906;SCHEMBL19695663;(R)-SIPHOS-PE, 97%;(S)-SIPHOS-PE, 97%;AKOS015950896;AKOS015950899;AKOS025295381;(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-BIS(R)-1PHENYLETHYL]AMINE;CS-0037331;CS-0086066;J10005;J10006;A935141;1,1'-Spirobiindan-7,7'-diylbisoxy[bis[(R)-1-phenylethyl]amino]phosphine;(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine;(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine;(aR)-7,7'-[[Bis[(R)-alpha-methylbenzyl]amino]phosphinidenebisoxy]-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene];N,N-bis((R)-1-phenylethyl)-4,5,6,7-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-12-amine

Suppliers and Price of (S)-Siphos-PE
Supply Marketing:
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • Strem Chemicals
  • (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (S)-SIPHOS-PE
  • 100mg
  • $ 149.00
  • Strem Chemicals
  • (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (S)-SIPHOS-PE
  • 500mg
  • $ 594.00
  • Sigma-Aldrich
  • (R)-SIPHOS-PE 97%
  • 250 mg
  • $ 400.00
  • Sigma-Aldrich
  • (S)-SIPHOS-PE 97%
  • 250mg
  • $ 388.00
  • Sigma-Aldrich
  • (R)-SIPHOS-PE 97%
  • 50 mg
  • $ 109.00
  • Sigma-Aldrich
  • (S)-SIPHOS-PE 97%
  • 50mg
  • $ 103.00
  • American Custom Chemicals Corporation
  • (S)-SIPHOS-PE 95.00%
  • 250MG
  • $ 850.14
  • American Custom Chemicals Corporation
  • (S)-SIPHOS-PE 95.00%
  • 50MG
  • $ 621.89
Total 15 raw suppliers
Chemical Property of (S)-Siphos-PE
Chemical Property:
  • Melting Point:99-101°C 
  • Boiling Point:617.8±65.0 °C(Predicted) 
  • PKA:0.40±0.20(Predicted) 
  • PSA：35.29000 
  • LogP:8.68760 
  • Storage Temp.:?20°C 
  • Sensitive.:moisture sensitive 
  • XLogP3:8.6
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:3
  • Rotatable Bond Count:5
  • Exact Mass:505.21706626
  • Heavy Atom Count:37
  • Complexity:716
Purity/Quality:

98% *data from raw suppliers

(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine, min. 98% (S)-SIPHOS-PE *data from reagent suppliers

Safty Information:
  • Pictogram(s):  
  • Hazard Codes:Xi 
  • Statements: 36/37/38 
  • Safety Statements: 26-36/37 
MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:
  • Canonical SMILES:CC(C1=CC=CC=C1)N(C(C)C2=CC=CC=C2)P3OC4=CC=CC5=C4C6(CC5)CCC7=C6C(=CC=C7)O3
  • Isomeric SMILES:C[C@H](C1=CC=CC=C1)N([C@H](C)C2=CC=CC=C2)P3OC4=CC=CC5=C4C6(CC5)CCC7=C6C(=CC=C7)O3
  • Uses (S)-SIPHOS-PE is a chiral spiro phosphoramidate ligand that can be used to synthesize: Spiroindolenines by Pd-catalyzed intramolecular dearomative arylation of haloaryl-3-substituted indoles. Enantioselective conjugate addition compound by Cu-catalyzed 1,4-addition of diethylzinc (Et2Zn) to cyclic enones. Octaketide natural products via rhodium-phosphoramidite catalyzed alkene hydroacylation.
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