Triallylborane

Base Information

• Chemical Name: Triallylborane
• CAS No.: 688-61-9
• Molecular Formula: C₉H₁₅B
• Molecular Weight: 134.029
• DSSTox Substance ID: DTXSID90416090
• Nikkaji Number: J944.336C
• Wikidata: Q82225252
• Mol file: 688-61-9.mol

Synonyms:TRIALLYLBORANE;tris(prop-2-enyl)borane;688-61-9;TRIS(PROP-2-EN-1-YL)BORANE;triallyl borane;DTXSID90416090;ULHDSMBBOXGDRG-UHFFFAOYSA-N;MFCD00039823;AKOS015904417;InChI=1/C9H15B/c1-4-7-10(8-5-2)9-6-3/h4-6H,1-3,7-9H

Chemical Property of Triallylborane

Chemical Property:

• PSA: 0.00000
• LogP: 3.03920
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 134.1266806
• Heavy Atom Count: 10
• Complexity: 92.1

Purity/Quality:

98%min ^*data from raw suppliers

TRIALLYLBORANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(CC=C)(CC=C)CC=C

Technology Process of Triallylborane

There total 1 articles about Triallylborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trimethyl(allyl)stannane (762-73-2) + boron tribromide (10294-33-4) → 2-propenyldibromoborane (126566-51-6) + Triallylborane (688-61-9,53588-88-8,90721-85-0,151452-33-4,151452-35-6) + dibromomethylborane (17933-16-3) + dimethyltin dibromide (2767-47-7) + trimethyltin bromide (1066-44-0)

Guidance literature:

In chloroform-d1; react. at -10°C; further unidentified product;

DOI:10.1016/S0020-1693(00)83155-2

Reference yield: 100.0%

Triallylborane (688-61-9,53588-88-8,90721-85-0,151452-33-4,151452-35-6) + (1R,2R)-1,2-bis(2-cyclooctylphenyl)ethane-1,2-diol → (4R,5R)-2-allyl-4,5-bis(2-cyclooctylphenyl)-1,3,2-dioxaborolane

Guidance literature:

With triethylamine; In tetrahydrofuran; at 75 ℃; for 2h;

DOI:10.1021/ja8016076

Reference yield: 94.0%

Triallylborane (688-61-9,53588-88-8,90721-85-0,151452-33-4,151452-35-6) + para-chloroacetophenone (99-91-2) → (R)-2-(4'-chlorophenyl)-4-penten-2-ol

Guidance literature:

Triallylborane; With (R)-3,3'-bis(trifluoromethyl)-2,2'-dihydroxy-1,1'-binaphthyl; In tetrahydrofuran; for 1h; Heating;

para-chloroacetophenone; In toluene; at -78 - -40 ℃; for 48h;

DOI:10.1021/ol0490882

upstream raw materials:

trimethyl(allyl)stannane

boron tribromide

Downstream raw materials:

3-allyl-5-cyclohex-1-enyl-1-methoxy-1,2,3,4-tetrahydro-borinine

(5E,7E)-4-Methyl-8-phenyl-octa-1,5,7-trien-4-ol

3-allyl-7-cyclohex-1-enyl-3-bora-bicyclo[3.3.1]non-6-ene

6,10-dimethylundeca-1,5,9-trien-4-ol