ETIOPORPHYRIN I NICKEL

Base Information

• Chemical Name: ETIOPORPHYRIN I NICKEL
• CAS No.: 14055-19-7
• Molecular Formula: C₃₂H₃₆N₄Ni
• Molecular Weight: 535.355
• Mol file: 14055-19-7.mol

Synonyms:EtioporphyrinI, Ni deriv. (6CI); Nickel, [2,7,12,17-tetraethyl-3,8,13,18-tetramethyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-,(SP-4-1)-; Nickel, [2,7,12,17-tetraethyl-3,8,13,18-tetramethylporphinato(2-)]-(8CI); Nickel, [etioporphyrin 1-ato(2-)]- (7CI); 21H,23H-Porphine,2,7,12,17-tetraethyl-3,8,13,18-tetramethyl-, nickel complex; 21H,23H-Porphine,nickel deriv.; Nickel etioporphyrin I; Nickel(2+) etioporphyrin; Nickel(II)etioporphyrin I

Chemical Property of ETIOPORPHYRIN I NICKEL

Chemical Property:

• PSA: 34.58000
• LogP: 4.84600

Purity/Quality:

98%,99%, ^*data from raw suppliers

Etioporphyrin I nickel ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22
• Safety Statements: 36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Etioporphyrin I Nickel is a platinum (II) based porphyrin porphyrin with the potential to be a transistor. Acts as a catalyst in metal porphyrins for hydrocarbon cracking or hydrogenation. Ni-EP can be used to fabricate a field effect transistor (FET).

Technology Process of ETIOPORPHYRIN I NICKEL

There total 2 articles about ETIOPORPHYRIN I NICKEL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 3.0%

4-ethyl-5-formyl-3-methyl-pyrrole-2-carboxylic acid (4949-42-2) + nickel diacetate (373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6) → [(2,7,12,17-tetramethyl-3,8,13,18-tetraethylporphyrinato)nickel(II)] (14055-19-7)

Guidance literature:

With sodium acetate; triphenylphosphine; trifluoroacetic acid; In ethanol; refluxing substituted pyrrole with CF3CO2H for 30 min, addn. of AcONa, metal salt and PPh3, refluxing for 24 h; evapn. (vac.), extn. into Et2O, chromy. (Al2O3, Et2O), recrystn. (Et2O/pentane=1:3);

DOI:10.1016/0020-1693(95)04747-6

Reference yield:

etioporphyrin I + nickel diacetate (373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6) → etioporphyrine-I nickel (II) (14055-19-7)

Guidance literature:

In acetic acid; boiling Ni acetate with C32H38N4 in glacial acetic acid until absorpion spectrum of free base disappears, distilling off solvent in vac.;; washing residue with H2O, recrystn. from pyridine, drying at 100°C;;

upstream raw materials:

nickel diacetate

4-ethyl-5-formyl-3-methyl-pyrrole-2-carboxylic acid

Refernces