7-TETRADECANONE

Base Information

• Chemical Name: 7-TETRADECANONE
• CAS No.: 6137-34-4
• Molecular Formula: C14H28O
• Molecular Weight: 212.376
• Hs Code.: 2914190090
• Mol file: 6137-34-4.mol

Synonyms:7-TETRADECANONE

Chemical Property of 7-TETRADECANONE

Chemical Property:

• Vapor Pressure: 0.00468mmHg at 25°C
• Melting Point: 38.18°C (estimate)
• Refractive Index: 1.434
• Boiling Point: 276.8°C at 760 mmHg
• Flash Point: 81.8°C
• PSA: 17.07000
• Density: 0.827g/cm³
• LogP: 4.88640

Purity/Quality:

99% ，98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 7-TETRADECANONE

There total 7 articles about 7-TETRADECANONE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetradecane (629-59-4) → tetradecan-7-ol (3981-79-1) + tetradecan-7-one (6137-34-4) + tetradecan-5-one (31857-89-3) + 6-tetradecanone (6836-42-6) + tetradecan-4-one (26496-20-8) + tetradecan-3-one (629-23-2)

Guidance literature:

With 2C₄H₁₂N⁽¹⁺⁾*6Na⁽¹⁺⁾*25H₂O*C₁₂H₁₂O₇₀Ru₂Te₂W₂₀^(8-); In neat (no solvent); Catalytic behavior;

DOI:10.1039/c6nj01914e

Reference yield:

n-heptan1ol (111-70-6) → 1-Heptene (592-76-7) + heptanal (111-71-7) + diheptyl ether (629-64-1) + tetradecan-7-one (6137-34-4)

Guidance literature:

zinc aluminate; at 424.85 ℃; for 2h; Further Variations:; Temperatures; Product distribution;

Reference yield:

orthoformic acid triethyl ester (122-51-0) → ethyl octan-2-yl carbonate (94149-27-6) + tetradecan-7-one (6137-34-4) + C7H15O3 (25748-61-2) + Diethyl carbonate (105-58-8,76619-83-5)

Guidance literature:

With 1-hexene; di-tert-butyl peroxide; at 140 ℃; for 2h; Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1007/BF00954092

upstream raw materials:

1-hexene

C₇H₁₅O₃

orthoformic acid triethyl ester

7-tetradecyne

Refernces

• 1、 Yusubov,Filimonov,Chi, Ki-Whan. "Oxidation of alkylphenylacetylenes and dialkylacetylenes on palladium catalysts in DMSO". . p. 649 - 653. Retrieved 2007/10/03.
• 2、 Khatuntsev, I.I.,Pastushenko, E.V.,Terent'ev, A.B.. "RADICAL REACTIONS OF ETHYL ORTHOFORMATE WITH 1-HEXENE". . p. 2109 - 2112. Retrieved 2007/10/02.