(3-Oxo-2-pent-2-ynylcyclopentyl)thioacetic acid, S-t-butyl ester

Base Information

• Chemical Name: (3-Oxo-2-pent-2-ynylcyclopentyl)thioacetic acid, S-t-butyl ester
• CAS No.: 68931-52-2
• Molecular Formula: C16H24O2S
• Molecular Weight: 0
• Mol file: 68931-52-2.mol

Synonyms:(3-Oxo-2-pent-2-ynylcyclopentyl)thioacetic acid, S-t-butyl ester

Chemical Property of (3-Oxo-2-pent-2-ynylcyclopentyl)thioacetic acid, S-t-butyl ester

Chemical Property:

• PSA: 59.44000
• LogP: 3.83360

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (3-Oxo-2-pent-2-ynylcyclopentyl)thioacetic acid, S-t-butyl ester

There total 3 articles about (3-Oxo-2-pent-2-ynylcyclopentyl)thioacetic acid, S-t-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

S-tert-butyl thioacetate (999-90-6) → Dehydrothiojasmonsaeure-S-t-butylester (68931-52-2)

Guidance literature:

Multi-step reaction with 3 steps

1: (i) LDA, THF, (ii) /BRN= 1209232/

2: 4N>F / tetrahydrofuran

3: 4N>F / tetrahydrofuran

With tetrabutyl ammonium fluoride; In tetrahydrofuran;

DOI:10.1002/hlca.19780610721

Reference yield:

(1-tert-butylsulfanyl-vinyloxy)trimethylsilane (63584-47-4) → Dehydrothiojasmonsaeure-S-t-butylester (68931-52-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 4N>F / tetrahydrofuran

2: 4N>F / tetrahydrofuran

With tetrabutyl ammonium fluoride; In tetrahydrofuran;

DOI:10.1002/hlca.19780610721

Reference yield:

1-bromo-pent-2-yne (16400-32-1) + (3-Trimethylsilanyloxy-cyclopent-2-enyl)-thioacetic acid S-tert-butyl ester (68931-44-2) → Dehydrothiojasmonsaeure-S-t-butylester (68931-52-2)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran;

DOI:10.1002/hlca.19780610721

upstream raw materials:

1-bromo-pent-2-yne

(3-Trimethylsilanyloxy-cyclopent-2-enyl)-thioacetic acid S-tert-butyl ester

S-tert-butyl thioacetate

(1-tert-butylsulfanyl-vinyloxy)trimethylsilane